Bis(tri­ethyl­ammonium) chloranilate

In the crystal structure of the title compound [systematic name: bis­(tri­ethyl­ammonium) 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-diolate], 2C(6)H(16)N(+)·C(6)Cl(2)O(4) (2−), the chloranilate anion lies on an inversion center. The tri­ethyl­ammonium cations are linked on both sides of the a...

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Detalles Bibliográficos
Autores principales: Gotoh, Kazuma, Maruyama, Shinpei, Ishida, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884448/
https://www.ncbi.nlm.nih.gov/pubmed/24427039
http://dx.doi.org/10.1107/S1600536813021405
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author Gotoh, Kazuma
Maruyama, Shinpei
Ishida, Hiroyuki
author_facet Gotoh, Kazuma
Maruyama, Shinpei
Ishida, Hiroyuki
author_sort Gotoh, Kazuma
collection PubMed
description In the crystal structure of the title compound [systematic name: bis­(tri­ethyl­ammonium) 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-diolate], 2C(6)H(16)N(+)·C(6)Cl(2)O(4) (2−), the chloranilate anion lies on an inversion center. The tri­ethyl­ammonium cations are linked on both sides of the anion via bifurcated N—H⋯(O,O) and weak C—H⋯O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C—H⋯O hydrogen bonds into a zigzag chain running along [01-1].
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spelling pubmed-38844482014-01-14 Bis(tri­ethyl­ammonium) chloranilate Gotoh, Kazuma Maruyama, Shinpei Ishida, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound [systematic name: bis­(tri­ethyl­ammonium) 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-diolate], 2C(6)H(16)N(+)·C(6)Cl(2)O(4) (2−), the chloranilate anion lies on an inversion center. The tri­ethyl­ammonium cations are linked on both sides of the anion via bifurcated N—H⋯(O,O) and weak C—H⋯O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C—H⋯O hydrogen bonds into a zigzag chain running along [01-1]. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884448/ /pubmed/24427039 http://dx.doi.org/10.1107/S1600536813021405 Text en © Gotoh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gotoh, Kazuma
Maruyama, Shinpei
Ishida, Hiroyuki
Bis(tri­ethyl­ammonium) chloranilate
title Bis(tri­ethyl­ammonium) chloranilate
title_full Bis(tri­ethyl­ammonium) chloranilate
title_fullStr Bis(tri­ethyl­ammonium) chloranilate
title_full_unstemmed Bis(tri­ethyl­ammonium) chloranilate
title_short Bis(tri­ethyl­ammonium) chloranilate
title_sort bis(tri­ethyl­ammonium) chloranilate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884448/
https://www.ncbi.nlm.nih.gov/pubmed/24427039
http://dx.doi.org/10.1107/S1600536813021405
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AT maruyamashinpei bistriethylammoniumchloranilate
AT ishidahiroyuki bistriethylammoniumchloranilate

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