2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile

The title compound, C(21)H(13)N(3)O, crystallizes with two independent molecules with similar conformations per asymmetric unit. The dihydrofuran rings are essentially planar with maximum deviations of 0.017 (1) and 0.006 (1) Å for the O atoms. The dihedral angles between the di­hydro­furan ring and...

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Detalles Bibliográficos
Autores principales: Bhuiyan, M. Delower H., Gainsford, Graeme J., Kay, Andrew, Anderson, Jack
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884449/
https://www.ncbi.nlm.nih.gov/pubmed/24427012
http://dx.doi.org/10.1107/S1600536813020849
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author Bhuiyan, M. Delower H.
Gainsford, Graeme J.
Kay, Andrew
Anderson, Jack
author_facet Bhuiyan, M. Delower H.
Gainsford, Graeme J.
Kay, Andrew
Anderson, Jack
author_sort Bhuiyan, M. Delower H.
collection PubMed
description The title compound, C(21)H(13)N(3)O, crystallizes with two independent molecules with similar conformations per asymmetric unit. The dihydrofuran rings are essentially planar with maximum deviations of 0.017 (1) and 0.006 (1) Å for the O atoms. The dihedral angles between the di­hydro­furan ring and the attached phenyl rings are 79.90 (6) and 82.07 (6)° in one mol­ecule and 79.36 (6) and 72.26 (6)° in the other. In the crystal, the molecules are linked by weak C—H⋯π and C—H⋯N inter­actions similar to those in other closely related crystals. The replacement of appended methyl by phenyl groups has not significantly affected the dihydrofuran ring structure or the crystal packing interactions.
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spelling pubmed-38844492014-01-14 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile Bhuiyan, M. Delower H. Gainsford, Graeme J. Kay, Andrew Anderson, Jack Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(13)N(3)O, crystallizes with two independent molecules with similar conformations per asymmetric unit. The dihydrofuran rings are essentially planar with maximum deviations of 0.017 (1) and 0.006 (1) Å for the O atoms. The dihedral angles between the di­hydro­furan ring and the attached phenyl rings are 79.90 (6) and 82.07 (6)° in one mol­ecule and 79.36 (6) and 72.26 (6)° in the other. In the crystal, the molecules are linked by weak C—H⋯π and C—H⋯N inter­actions similar to those in other closely related crystals. The replacement of appended methyl by phenyl groups has not significantly affected the dihydrofuran ring structure or the crystal packing interactions. International Union of Crystallography 2013-08-03 /pmc/articles/PMC3884449/ /pubmed/24427012 http://dx.doi.org/10.1107/S1600536813020849 Text en © Bhuiyan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bhuiyan, M. Delower H.
Gainsford, Graeme J.
Kay, Andrew
Anderson, Jack
2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title_full 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title_fullStr 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title_full_unstemmed 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title_short 2-(3-Cyano-4-methyl-5,5-diphenyl-5H-furan-2-yl­idene)malono­nitrile
title_sort 2-(3-cyano-4-methyl-5,5-diphenyl-5h-furan-2-yl­idene)malono­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884449/
https://www.ncbi.nlm.nih.gov/pubmed/24427012
http://dx.doi.org/10.1107/S1600536813020849
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AT kayandrew 23cyano4methyl55diphenyl5hfuran2ylidenemalononitrile
AT andersonjack 23cyano4methyl55diphenyl5hfuran2ylidenemalononitrile

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