Cargando…

catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]

In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octa­hedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-uniqu...

Descripción completa

Detalles Bibliográficos
Autores principales: Luo, Feihua, Du, Huirong, Yang, Li, Zhang, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884458/
https://www.ncbi.nlm.nih.gov/pubmed/24427010
http://dx.doi.org/10.1107/S1600536813024161
Descripción
Sumario:In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octa­hedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxyl­ate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O—H⋯N hydrogen bonds and π–π inter­actions, with a centroid–centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C—H⋯O and C—H⋯N hydrogen bonds complete a three-dimensional network. An intra­molecular O—H⋯O hydrogen bond is also observed.