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catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octahedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-uniqu...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884458/ https://www.ncbi.nlm.nih.gov/pubmed/24427010 http://dx.doi.org/10.1107/S1600536813024161 |
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author | Luo, Feihua Du, Huirong Yang, Li Zhang, Ping |
author_facet | Luo, Feihua Du, Huirong Yang, Li Zhang, Ping |
author_sort | Luo, Feihua |
collection | PubMed |
description | In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octahedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxylate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O—H⋯N hydrogen bonds and π–π interactions, with a centroid–centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C—H⋯O and C—H⋯N hydrogen bonds complete a three-dimensional network. An intramolecular O—H⋯O hydrogen bond is also observed. |
format | Online Article Text |
id | pubmed-3884458 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844582014-01-14 catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] Luo, Feihua Du, Huirong Yang, Li Zhang, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octahedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxylate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O—H⋯N hydrogen bonds and π–π interactions, with a centroid–centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C—H⋯O and C—H⋯N hydrogen bonds complete a three-dimensional network. An intramolecular O—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-08-31 /pmc/articles/PMC3884458/ /pubmed/24427010 http://dx.doi.org/10.1107/S1600536813024161 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Luo, Feihua Du, Huirong Yang, Li Zhang, Ping catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title |
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title_full |
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title_fullStr |
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title_full_unstemmed |
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title_short |
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] |
title_sort | catena-poly[{μ-n′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κo)nickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884458/ https://www.ncbi.nlm.nih.gov/pubmed/24427010 http://dx.doi.org/10.1107/S1600536813024161 |
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