Cargando…

catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]

In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octa­hedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-uniqu...

Descripción completa

Detalles Bibliográficos
Autores principales: Luo, Feihua, Du, Huirong, Yang, Li, Zhang, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884458/
https://www.ncbi.nlm.nih.gov/pubmed/24427010
http://dx.doi.org/10.1107/S1600536813024161
_version_ 1782298595471392768
author Luo, Feihua
Du, Huirong
Yang, Li
Zhang, Ping
author_facet Luo, Feihua
Du, Huirong
Yang, Li
Zhang, Ping
author_sort Luo, Feihua
collection PubMed
description In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octa­hedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxyl­ate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O—H⋯N hydrogen bonds and π–π inter­actions, with a centroid–centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C—H⋯O and C—H⋯N hydrogen bonds complete a three-dimensional network. An intra­molecular O—H⋯O hydrogen bond is also observed.
format Online
Article
Text
id pubmed-3884458
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38844582014-01-14 catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)] Luo, Feihua Du, Huirong Yang, Li Zhang, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(16)H(12)N(2)O(5))(CH(3)OH)](n), the unique Ni(II) ion is coordinated in a distorted octa­hedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxyl­ate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O—H⋯N hydrogen bonds and π–π inter­actions, with a centroid–centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C—H⋯O and C—H⋯N hydrogen bonds complete a three-dimensional network. An intra­molecular O—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-08-31 /pmc/articles/PMC3884458/ /pubmed/24427010 http://dx.doi.org/10.1107/S1600536813024161 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Feihua
Du, Huirong
Yang, Li
Zhang, Ping
catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title_full catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title_fullStr catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title_full_unstemmed catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title_short catena-Poly[{μ-N′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κO)nickel(II)]
title_sort catena-poly[{μ-n′-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-κo)nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884458/
https://www.ncbi.nlm.nih.gov/pubmed/24427010
http://dx.doi.org/10.1107/S1600536813024161
work_keys_str_mv AT luofeihua catenapolymn2carboxylatomethoxybenzylidene2hydroxybenzohydrazidatomethanolkonickelii
AT duhuirong catenapolymn2carboxylatomethoxybenzylidene2hydroxybenzohydrazidatomethanolkonickelii
AT yangli catenapolymn2carboxylatomethoxybenzylidene2hydroxybenzohydrazidatomethanolkonickelii
AT zhangping catenapolymn2carboxylatomethoxybenzylidene2hydroxybenzohydrazidatomethanolkonickelii