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1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar

In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rin...

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Autores principales: Zhang, Qiurong, Zhou, Guangqiang, He, Peng, Chen, Xuebin, Liu, Hongmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884459/
https://www.ncbi.nlm.nih.gov/pubmed/24427038
http://dx.doi.org/10.1107/S1600536813021776
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author Zhang, Qiurong
Zhou, Guangqiang
He, Peng
Chen, Xuebin
Liu, Hongmin
author_facet Zhang, Qiurong
Zhou, Guangqiang
He, Peng
Chen, Xuebin
Liu, Hongmin
author_sort Zhang, Qiurong
collection PubMed
description In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rings (all atoms) is 59.05 (12)°. The five-membered ring linked to the ethynyl susbtituent is twisted about a C—C bond; the cis-fused adjacent ring is twisted about a C—O bond [dihedral angle between the rings (all atoms) = 71.78 (12)°]. Two intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, generating [001] chains.
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spelling pubmed-38844592014-01-14 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar Zhang, Qiurong Zhou, Guangqiang He, Peng Chen, Xuebin Liu, Hongmin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rings (all atoms) is 59.05 (12)°. The five-membered ring linked to the ethynyl susbtituent is twisted about a C—C bond; the cis-fused adjacent ring is twisted about a C—O bond [dihedral angle between the rings (all atoms) = 71.78 (12)°]. Two intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, generating [001] chains. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884459/ /pubmed/24427038 http://dx.doi.org/10.1107/S1600536813021776 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Qiurong
Zhou, Guangqiang
He, Peng
Chen, Xuebin
Liu, Hongmin
1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title_full 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title_fullStr 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title_full_unstemmed 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title_short 1,2:1′,2′-Di-O-iso­propyl­idenedi­furan­ose-C12 higher carbon sugar
title_sort 1,2:1′,2′-di-o-iso­propyl­idenedi­furan­ose-c12 higher carbon sugar
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884459/
https://www.ncbi.nlm.nih.gov/pubmed/24427038
http://dx.doi.org/10.1107/S1600536813021776
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