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1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar
In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rin...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884459/ https://www.ncbi.nlm.nih.gov/pubmed/24427038 http://dx.doi.org/10.1107/S1600536813021776 |
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author | Zhang, Qiurong Zhou, Guangqiang He, Peng Chen, Xuebin Liu, Hongmin |
author_facet | Zhang, Qiurong Zhou, Guangqiang He, Peng Chen, Xuebin Liu, Hongmin |
author_sort | Zhang, Qiurong |
collection | PubMed |
description | In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rings (all atoms) is 59.05 (12)°. The five-membered ring linked to the ethynyl susbtituent is twisted about a C—C bond; the cis-fused adjacent ring is twisted about a C—O bond [dihedral angle between the rings (all atoms) = 71.78 (12)°]. Two intramolecular O—H⋯O hydrogen bonds occur. In the crystal, molecules are linked by O—H⋯O hydrogen bonds, generating [001] chains. |
format | Online Article Text |
id | pubmed-3884459 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844592014-01-14 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar Zhang, Qiurong Zhou, Guangqiang He, Peng Chen, Xuebin Liu, Hongmin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(28)O(8), the five-membered ring with one O atom attached to the ethyl substituent has a twisted conformation about the C—O bond. The adjacent cis-fused ring with two O atoms also has a twisted conformation about one of the C—O bonds. The dihedral angle between these rings (all atoms) is 59.05 (12)°. The five-membered ring linked to the ethynyl susbtituent is twisted about a C—C bond; the cis-fused adjacent ring is twisted about a C—O bond [dihedral angle between the rings (all atoms) = 71.78 (12)°]. Two intramolecular O—H⋯O hydrogen bonds occur. In the crystal, molecules are linked by O—H⋯O hydrogen bonds, generating [001] chains. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884459/ /pubmed/24427038 http://dx.doi.org/10.1107/S1600536813021776 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Qiurong Zhou, Guangqiang He, Peng Chen, Xuebin Liu, Hongmin 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title | 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title_full | 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title_fullStr | 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title_full_unstemmed | 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title_short | 1,2:1′,2′-Di-O-isopropylidenedifuranose-C12 higher carbon sugar |
title_sort | 1,2:1′,2′-di-o-isopropylidenedifuranose-c12 higher carbon sugar |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884459/ https://www.ncbi.nlm.nih.gov/pubmed/24427038 http://dx.doi.org/10.1107/S1600536813021776 |
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