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2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C(25)H(15)ClN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.152 (3) Å for the C atom to which the 4-chloro-2-nitro­phenyl ring is attached. Its mean plane is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihed...

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Autores principales: Gopinath, S., Sethusankar, K., Ramalingam, Bose Muthu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884462/
https://www.ncbi.nlm.nih.gov/pubmed/24427055
http://dx.doi.org/10.1107/S1600536813022253
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author Gopinath, S.
Sethusankar, K.
Ramalingam, Bose Muthu
Mohanakrishnan, Arasambattu K.
author_facet Gopinath, S.
Sethusankar, K.
Ramalingam, Bose Muthu
Mohanakrishnan, Arasambattu K.
author_sort Gopinath, S.
collection PubMed
description In the title compound, C(25)H(15)ClN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.152 (3) Å for the C atom to which the 4-chloro-2-nitro­phenyl ring is attached. Its mean plane is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 82.64 (14) and 79.89 (13)°, respectively. The N atom of the nitro group deviates by 0.032 (3) Å from the benzene ring to which it is attached. The mol­ecular structure features intra­molecular O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, forming a two-dimensional network lying parallel to (001). There are also R (4) (3)(28) supra­molecular graph-set ring motifs enclosed within these networks.
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spelling pubmed-38844622014-01-14 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde Gopinath, S. Sethusankar, K. Ramalingam, Bose Muthu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(15)ClN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.152 (3) Å for the C atom to which the 4-chloro-2-nitro­phenyl ring is attached. Its mean plane is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 82.64 (14) and 79.89 (13)°, respectively. The N atom of the nitro group deviates by 0.032 (3) Å from the benzene ring to which it is attached. The mol­ecular structure features intra­molecular O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, forming a two-dimensional network lying parallel to (001). There are also R (4) (3)(28) supra­molecular graph-set ring motifs enclosed within these networks. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884462/ /pubmed/24427055 http://dx.doi.org/10.1107/S1600536813022253 Text en © Gopinath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gopinath, S.
Sethusankar, K.
Ramalingam, Bose Muthu
Mohanakrishnan, Arasambattu K.
2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_fullStr 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full_unstemmed 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_short 2-(4-Chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_sort 2-(4-chloro-2-nitro­phen­yl)-9-phenyl­sulfonyl-9h-carbazole-3-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884462/
https://www.ncbi.nlm.nih.gov/pubmed/24427055
http://dx.doi.org/10.1107/S1600536813022253
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