Lithium vanado(V)molybdate(VI), Li[VMoO(6)]

Brannerite-type Li[VMoO(6)] has been synthesized by a solid state reaction route. The V and Mo atoms statistically occupy the same site with mirror symmetry and are octa­hedrally surrounded by O atoms. The framework is two-dimensional and is built up from edge-sharing (V,Mo)O(6) octa­hedra forming (...

Descripción completa

Detalles Bibliográficos
Autores principales: Ezzine Yahmed, Safa, Nasri, Rawia, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884465/
https://www.ncbi.nlm.nih.gov/pubmed/24426977
http://dx.doi.org/10.1107/S1600536813022411
Descripción
Sumario:Brannerite-type Li[VMoO(6)] has been synthesized by a solid state reaction route. The V and Mo atoms statistically occupy the same site with mirror symmetry and are octa­hedrally surrounded by O atoms. The framework is two-dimensional and is built up from edge-sharing (V,Mo)O(6) octa­hedra forming (VMoO(6))(∞) layers that run parallel to the (001) plane. Li(+) ions are situated in position with symmetry 2/m in the inter­layer space. The bond-valence analysis reveals that the Li(+) ionic conductivity is along the [010] and [110] directions, and shows that this material may have inter­esting conduction properties. This simulation proposes a model of the lithium conduction pathways.

Ejemplares similares