Lithium vanado(V)molybdate(VI), Li[VMoO(6)]

Brannerite-type Li[VMoO(6)] has been synthesized by a solid state reaction route. The V and Mo atoms statistically occupy the same site with mirror symmetry and are octa­hedrally surrounded by O atoms. The framework is two-dimensional and is built up from edge-sharing (V,Mo)O(6) octa­hedra forming (...

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Autores principales: Ezzine Yahmed, Safa, Nasri, Rawia, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884465/
https://www.ncbi.nlm.nih.gov/pubmed/24426977
http://dx.doi.org/10.1107/S1600536813022411
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author Ezzine Yahmed, Safa
Nasri, Rawia
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Ezzine Yahmed, Safa
Nasri, Rawia
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Ezzine Yahmed, Safa
collection PubMed
description Brannerite-type Li[VMoO(6)] has been synthesized by a solid state reaction route. The V and Mo atoms statistically occupy the same site with mirror symmetry and are octa­hedrally surrounded by O atoms. The framework is two-dimensional and is built up from edge-sharing (V,Mo)O(6) octa­hedra forming (VMoO(6))(∞) layers that run parallel to the (001) plane. Li(+) ions are situated in position with symmetry 2/m in the inter­layer space. The bond-valence analysis reveals that the Li(+) ionic conductivity is along the [010] and [110] directions, and shows that this material may have inter­esting conduction properties. This simulation proposes a model of the lithium conduction pathways.
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spelling pubmed-38844652014-01-14 Lithium vanado(V)molybdate(VI), Li[VMoO(6)] Ezzine Yahmed, Safa Nasri, Rawia Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Brannerite-type Li[VMoO(6)] has been synthesized by a solid state reaction route. The V and Mo atoms statistically occupy the same site with mirror symmetry and are octa­hedrally surrounded by O atoms. The framework is two-dimensional and is built up from edge-sharing (V,Mo)O(6) octa­hedra forming (VMoO(6))(∞) layers that run parallel to the (001) plane. Li(+) ions are situated in position with symmetry 2/m in the inter­layer space. The bond-valence analysis reveals that the Li(+) ionic conductivity is along the [010] and [110] directions, and shows that this material may have inter­esting conduction properties. This simulation proposes a model of the lithium conduction pathways. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884465/ /pubmed/24426977 http://dx.doi.org/10.1107/S1600536813022411 Text en © Ezzine Yahmed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ezzine Yahmed, Safa
Nasri, Rawia
Zid, Mohamed Faouzi
Driss, Ahmed
Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title_full Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title_fullStr Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title_full_unstemmed Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title_short Lithium vanado(V)molybdate(VI), Li[VMoO(6)]
title_sort lithium vanado(v)molybdate(vi), li[vmoo(6)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884465/
https://www.ncbi.nlm.nih.gov/pubmed/24426977
http://dx.doi.org/10.1107/S1600536813022411
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AT nasrirawia lithiumvanadovmolybdatevilivmoo6
AT zidmohamedfaouzi lithiumvanadovmolybdatevilivmoo6
AT drissahmed lithiumvanadovmolybdatevilivmoo6

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