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Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate

In the crystal structure of the title compound, [Pd(2)(C(36)H(42)N(6))Cl(2)](ClO(4))(2)·2C(3)H(7)NO·2CH(3)OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a c...

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Detalles Bibliográficos
Autores principales: Oda, Kohei, Funahashi, Yasuhiro, Masuda, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884468/
https://www.ncbi.nlm.nih.gov/pubmed/24427008
http://dx.doi.org/10.1107/S1600536813022666
Descripción
Sumario:In the crystal structure of the title compound, [Pd(2)(C(36)H(42)N(6))Cl(2)](ClO(4))(2)·2C(3)H(7)NO·2CH(3)OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a chloride ion. The Pd(II) complex cations and the methanol mol­ecules are linked through N—H⋯O and O—H⋯O hydrogen bonds, forming a zigzag chain along [101]. An intra­molecular N—H⋯Cl hydrogen bond is also observed.