Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate

In the crystal structure of the title compound, [Pd(2)(C(36)H(42)N(6))Cl(2)](ClO(4))(2)·2C(3)H(7)NO·2CH(3)OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a c...

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Detalles Bibliográficos
Autores principales: Oda, Kohei, Funahashi, Yasuhiro, Masuda, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884468/
https://www.ncbi.nlm.nih.gov/pubmed/24427008
http://dx.doi.org/10.1107/S1600536813022666
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author Oda, Kohei
Funahashi, Yasuhiro
Masuda, Hideki
author_facet Oda, Kohei
Funahashi, Yasuhiro
Masuda, Hideki
author_sort Oda, Kohei
collection PubMed
description In the crystal structure of the title compound, [Pd(2)(C(36)H(42)N(6))Cl(2)](ClO(4))(2)·2C(3)H(7)NO·2CH(3)OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a chloride ion. The Pd(II) complex cations and the methanol mol­ecules are linked through N—H⋯O and O—H⋯O hydrogen bonds, forming a zigzag chain along [101]. An intra­molecular N—H⋯Cl hydrogen bond is also observed.
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spelling pubmed-38844682014-01-14 Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate Oda, Kohei Funahashi, Yasuhiro Masuda, Hideki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Pd(2)(C(36)H(42)N(6))Cl(2)](ClO(4))(2)·2C(3)H(7)NO·2CH(3)OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a chloride ion. The Pd(II) complex cations and the methanol mol­ecules are linked through N—H⋯O and O—H⋯O hydrogen bonds, forming a zigzag chain along [101]. An intra­molecular N—H⋯Cl hydrogen bond is also observed. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884468/ /pubmed/24427008 http://dx.doi.org/10.1107/S1600536813022666 Text en © Oda et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oda, Kohei
Funahashi, Yasuhiro
Masuda, Hideki
Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title_full Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title_fullStr Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title_full_unstemmed Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title_short Di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per­chlor­ate) N,N-di­methyl­formamide disolvate methanol disolvate
title_sort di­chlorido­[6,8,22,24,34,36-hexa­methyl-33,35-diaza-3,11,19,27-tetra­azonia­penta­cyclo[27.3.1.1(5,9).1(13,17).1(21,25)]hexa­triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca­ene-κ(6) n (3),n (11),n (19),n (27),n (33),n (35)]dipalladium(ii) bis(per­chlor­ate) n,n-di­methyl­formamide disolvate methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884468/
https://www.ncbi.nlm.nih.gov/pubmed/24427008
http://dx.doi.org/10.1107/S1600536813022666
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AT funahashiyasuhiro dichlorido6822243436hexamethyl3335diaza3111927tetraazoniapentacyclo27311591131712125hexatriaconta1335793413151735212325362931dodecaenek6n3n11n19n27n33n35dipalladiumiibisperchloratenndimethylformamidedisolvatemethanoldisolvate
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