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(2E)-3-(2-Chloro-7-methylquinolin-3-yl)-1-(6-chloro-2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-one ethanol monosolvate
In the title ethanol solvate, C(29)H(20)Cl(2)N(2)O·C(2)H(5)OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [C(p)—C—C=O and C=C—C—C(p) (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridgi...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884470/ https://www.ncbi.nlm.nih.gov/pubmed/24427050 http://dx.doi.org/10.1107/S1600536813022022 |
Sumario: | In the title ethanol solvate, C(29)H(20)Cl(2)N(2)O·C(2)H(5)OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [C(p)—C—C=O and C=C—C—C(p) (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridging prop-2-en-1-one residue [O=C—C=C torsion angle = −4.1 (3)°]. The ethanol solvent molecule is disordered over two positions of equal occupancy and is located close to a centre of inversion. These molecules reside in cavities defined by the organic molecules, which are connected into a three-dimensional architecture by C—H⋯Cl, C—H⋯O and C—H⋯N interactions, as well as π–π contacts [inter-centroid distances = 3.5853 (10) and 3.8268 (11) Å], each involving pyridyl rings. |
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