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(2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate

In the title ethanol solvate, C(29)H(20)Cl(2)N(2)O·C(2)H(5)OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [C(p)—C—C=O and C=C—C—C(p) (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridgi...

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Autores principales: Prasath, R., Sarveswari, S., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884470/
https://www.ncbi.nlm.nih.gov/pubmed/24427050
http://dx.doi.org/10.1107/S1600536813022022
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author Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Prasath, R.
collection PubMed
description In the title ethanol solvate, C(29)H(20)Cl(2)N(2)O·C(2)H(5)OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [C(p)—C—C=O and C=C—C—C(p) (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridging prop-2-en-1-one residue [O=C—C=C torsion angle = −4.1 (3)°]. The ethanol solvent mol­ecule is disordered over two positions of equal occupancy and is located close to a centre of inversion. These mol­ecules reside in cavities defined by the organic mol­ecules, which are connected into a three-dimensional architecture by C—H⋯Cl, C—H⋯O and C—H⋯N inter­actions, as well as π–π contacts [inter-centroid distances = 3.5853 (10) and 3.8268 (11) Å], each involving pyridyl rings.
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spelling pubmed-38844702014-01-14 (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title ethanol solvate, C(29)H(20)Cl(2)N(2)O·C(2)H(5)OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [C(p)—C—C=O and C=C—C—C(p) (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridging prop-2-en-1-one residue [O=C—C=C torsion angle = −4.1 (3)°]. The ethanol solvent mol­ecule is disordered over two positions of equal occupancy and is located close to a centre of inversion. These mol­ecules reside in cavities defined by the organic mol­ecules, which are connected into a three-dimensional architecture by C—H⋯Cl, C—H⋯O and C—H⋯N inter­actions, as well as π–π contacts [inter-centroid distances = 3.5853 (10) and 3.8268 (11) Å], each involving pyridyl rings. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884470/ /pubmed/24427050 http://dx.doi.org/10.1107/S1600536813022022 Text en © Prasath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
(2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title_full (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title_fullStr (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title_full_unstemmed (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title_short (2E)-3-(2-Chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
title_sort (2e)-3-(2-chloro-7-methyl­quinolin-3-yl)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884470/
https://www.ncbi.nlm.nih.gov/pubmed/24427050
http://dx.doi.org/10.1107/S1600536813022022
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