Tetra­hydro­alstonine

In the title compound, C(21)H(24)N(2)O(3) [systematic name: methyl (20α)-16,17-dide­hydro-19α-methyl-18-oxayohimban-16-carb­oxy­l­ate], the mol­ecule adopts an L-type conformation. The crystal packing is governed by one N—H⋯π and one C—H⋯π inter­actions. The crystal cohesion is ensured by inter­mole...

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Detalles Bibliográficos
Autores principales: Cachet, Xavier, Porée, François-Hugues, Michel, Sylvie, Lemoine, Pascale
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884471/
https://www.ncbi.nlm.nih.gov/pubmed/24427031
http://dx.doi.org/10.1107/S1600536813021168
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author Cachet, Xavier
Porée, François-Hugues
Michel, Sylvie
Lemoine, Pascale
author_facet Cachet, Xavier
Porée, François-Hugues
Michel, Sylvie
Lemoine, Pascale
author_sort Cachet, Xavier
collection PubMed
description In the title compound, C(21)H(24)N(2)O(3) [systematic name: methyl (20α)-16,17-dide­hydro-19α-methyl-18-oxayohimban-16-carb­oxy­l­ate], the mol­ecule adopts an L-type conformation. The crystal packing is governed by one N—H⋯π and one C—H⋯π inter­actions. The crystal cohesion is ensured by inter­molecular van der Waals contacts [shortest O⋯O contact = 3.199 (2) Å].
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spelling pubmed-38844712014-01-14 Tetra­hydro­alstonine Cachet, Xavier Porée, François-Hugues Michel, Sylvie Lemoine, Pascale Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(3) [systematic name: methyl (20α)-16,17-dide­hydro-19α-methyl-18-oxayohimban-16-carb­oxy­l­ate], the mol­ecule adopts an L-type conformation. The crystal packing is governed by one N—H⋯π and one C—H⋯π inter­actions. The crystal cohesion is ensured by inter­molecular van der Waals contacts [shortest O⋯O contact = 3.199 (2) Å]. International Union of Crystallography 2013-08-07 /pmc/articles/PMC3884471/ /pubmed/24427031 http://dx.doi.org/10.1107/S1600536813021168 Text en © Cachet et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cachet, Xavier
Porée, François-Hugues
Michel, Sylvie
Lemoine, Pascale
Tetra­hydro­alstonine
title Tetra­hydro­alstonine
title_full Tetra­hydro­alstonine
title_fullStr Tetra­hydro­alstonine
title_full_unstemmed Tetra­hydro­alstonine
title_short Tetra­hydro­alstonine
title_sort tetra­hydro­alstonine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884471/
https://www.ncbi.nlm.nih.gov/pubmed/24427031
http://dx.doi.org/10.1107/S1600536813021168
work_keys_str_mv AT cachetxavier tetrahydroalstonine
AT poreefrancoishugues tetrahydroalstonine
AT michelsylvie tetrahydroalstonine
AT lemoinepascale tetrahydroalstonine

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