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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S at...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884478/ https://www.ncbi.nlm.nih.gov/pubmed/24427000 http://dx.doi.org/10.1107/S1600536813023027 |
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author | Zhong, Kai-Long Duan, Cheng-Xian |
author_facet | Zhong, Kai-Long Duan, Cheng-Xian |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent molecule. The dihedral angle between the two chelating N(2)C(2) groups is 85.61 (8)°. The [NiSO(4)(C(10)H(8)N(2))(2)] and propane-1,2-diol units are held together by a pair of symmetry-related intermolecular O—H⋯O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent molecule is equally disordered over two positions. |
format | Online Article Text |
id | pubmed-3884478 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844782014-01-14 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate Zhong, Kai-Long Duan, Cheng-Xian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent molecule. The dihedral angle between the two chelating N(2)C(2) groups is 85.61 (8)°. The [NiSO(4)(C(10)H(8)N(2))(2)] and propane-1,2-diol units are held together by a pair of symmetry-related intermolecular O—H⋯O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent molecule is equally disordered over two positions. International Union of Crystallography 2013-08-21 /pmc/articles/PMC3884478/ /pubmed/24427000 http://dx.doi.org/10.1107/S1600536813023027 Text en © Zhong and Duan 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Duan, Cheng-Xian Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate |
title | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)nickel(II) propane-1,2-diol monosolvate |
title_full | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)nickel(II) propane-1,2-diol monosolvate |
title_fullStr | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)nickel(II) propane-1,2-diol monosolvate |
title_full_unstemmed | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)nickel(II) propane-1,2-diol monosolvate |
title_short | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)nickel(II) propane-1,2-diol monosolvate |
title_sort | bis(1,10-phenanthroline-κ(2)
n,n′)(sulfato-κ(2)
o,o′)nickel(ii) propane-1,2-diol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884478/ https://www.ncbi.nlm.nih.gov/pubmed/24427000 http://dx.doi.org/10.1107/S1600536813023027 |
work_keys_str_mv | AT zhongkailong bis110phenanthrolinek2nnsulfatok2oonickeliipropane12diolmonosolvate AT duanchengxian bis110phenanthrolinek2nnsulfatok2oonickeliipropane12diolmonosolvate |