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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate

In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octa­hedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S at...

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Autores principales: Zhong, Kai-Long, Duan, Cheng-Xian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884478/
https://www.ncbi.nlm.nih.gov/pubmed/24427000
http://dx.doi.org/10.1107/S1600536813023027
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author Zhong, Kai-Long
Duan, Cheng-Xian
author_facet Zhong, Kai-Long
Duan, Cheng-Xian
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octa­hedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent mol­ecule. The dihedral angle between the two chelating N(2)C(2) groups is 85.61 (8)°. The [NiSO(4)(C(10)H(8)N(2))(2)] and propane-1,2-diol units are held together by a pair of symmetry-related inter­molecular O—H⋯O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent mol­ecule is equally disordered over two positions.
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spelling pubmed-38844782014-01-14 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate Zhong, Kai-Long Duan, Cheng-Xian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) atom exhibits a distorted octa­hedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent mol­ecule. The dihedral angle between the two chelating N(2)C(2) groups is 85.61 (8)°. The [NiSO(4)(C(10)H(8)N(2))(2)] and propane-1,2-diol units are held together by a pair of symmetry-related inter­molecular O—H⋯O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent mol­ecule is equally disordered over two positions. International Union of Crystallography 2013-08-21 /pmc/articles/PMC3884478/ /pubmed/24427000 http://dx.doi.org/10.1107/S1600536813023027 Text en © Zhong and Duan 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Duan, Cheng-Xian
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,2-diol monosolvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)nickel(ii) propane-1,2-diol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884478/
https://www.ncbi.nlm.nih.gov/pubmed/24427000
http://dx.doi.org/10.1107/S1600536813023027
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