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cis-Diaquatetrakis(1-butyl-1H-imidazole-κN (3))nickel(II) dichloride
In the title compound, [Ni(C(7)H(12)N(2))(4)(H(2)O)(2)]Cl(2), the nickel(II) ion has a distorted octahedral coordination environment. It is surrounded by three N atoms and one O atom occupying the equatorial plane, and one N and one O atom in the axial positions. The imidazole ring systems are incl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884482/ https://www.ncbi.nlm.nih.gov/pubmed/24426994 http://dx.doi.org/10.1107/S1600536813022496 |
Sumario: | In the title compound, [Ni(C(7)H(12)N(2))(4)(H(2)O)(2)]Cl(2), the nickel(II) ion has a distorted octahedral coordination environment. It is surrounded by three N atoms and one O atom occupying the equatorial plane, and one N and one O atom in the axial positions. The imidazole ring systems are inclined to one another with dihedral angles varying between 38.3 (4) and 74.1 (4)°. In the crystal, molecules are linked via O—H⋯Cl hydrogen bonds involving one Cl(−) anion and the water molecule in the equatorial plane, forming an inversion dimer-like arrangement. The water molecule in the axial position is hydrogen-bonded to both Cl(−) anions. There are also a number of C—H⋯Cl hydrogen bonds present, forming a three-dimensional structure. All four alkyl chains are disordered over two positions with refined occupancy ratios of 0.395 (15):0.605 (15), 0.658 (14):0.342 (14), 0.332 (11):0.668 (11) and 0.622 (12):0.378 (12). |
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