1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine

The mol­ecular structure of the title compound, C(16)H(16)N(2)O(2), is stabilized by intra­molecular O—H⋯N hydrogen bonds with S(6) graph-set motifs, so that the mol­ecule is almost planar, with a C=N—N=C torsion angle of −179.7 (2)° and a dihedral angle of 1.82 (12)° between the aromatic rings. In...

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Detalles Bibliográficos
Autores principales: Saravanan, B., Jayamani, A., Sengottuvelan, N., Chakkaravarthi, G., Manivannan, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884483/
https://www.ncbi.nlm.nih.gov/pubmed/24427035
http://dx.doi.org/10.1107/S160053681302148X
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author Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
author_facet Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
author_sort Saravanan, B.
collection PubMed
description The mol­ecular structure of the title compound, C(16)H(16)N(2)O(2), is stabilized by intra­molecular O—H⋯N hydrogen bonds with S(6) graph-set motifs, so that the mol­ecule is almost planar, with a C=N—N=C torsion angle of −179.7 (2)° and a dihedral angle of 1.82 (12)° between the aromatic rings. In the crystal, weak C—H⋯π inter­actions lead to the formation of a three-dimensional network.
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spelling pubmed-38844832014-01-14 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(16)H(16)N(2)O(2), is stabilized by intra­molecular O—H⋯N hydrogen bonds with S(6) graph-set motifs, so that the mol­ecule is almost planar, with a C=N—N=C torsion angle of −179.7 (2)° and a dihedral angle of 1.82 (12)° between the aromatic rings. In the crystal, weak C—H⋯π inter­actions lead to the formation of a three-dimensional network. International Union of Crystallography 2013-08-07 /pmc/articles/PMC3884483/ /pubmed/24427035 http://dx.doi.org/10.1107/S160053681302148X Text en © Saravanan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title_full 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title_fullStr 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title_full_unstemmed 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title_short 1,2-Bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
title_sort 1,2-bis(2-hy­droxy-5-methyl­benzyl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884483/
https://www.ncbi.nlm.nih.gov/pubmed/24427035
http://dx.doi.org/10.1107/S160053681302148X
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AT chakkaravarthig 12bis2hydroxy5methylbenzylidenehydrazine
AT manivannanv 12bis2hydroxy5methylbenzylidenehydrazine

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