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2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine

In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclo­penta­dienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and th...

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Detalles Bibliográficos
Autores principales: Gul, Rukhsana, Khan, Azim, Badshah, Amin, Tahir, M. Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884485/
https://www.ncbi.nlm.nih.gov/pubmed/24426986
http://dx.doi.org/10.1107/S1600536813021892
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author Gul, Rukhsana
Khan, Azim
Badshah, Amin
Tahir, M. Nawaz
author_facet Gul, Rukhsana
Khan, Azim
Badshah, Amin
Tahir, M. Nawaz
author_sort Gul, Rukhsana
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclo­penta­dienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and the guanidine group is 64.8 (2)°. One of the N—H groups forms both an intra- and an inter­molecular N—H⋯O hydrogen bond; the other N—H group does not form any hydrogen bonds. In the crystal, pairs of the inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers.
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spelling pubmed-38844852014-01-14 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine Gul, Rukhsana Khan, Azim Badshah, Amin Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclo­penta­dienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and the guanidine group is 64.8 (2)°. One of the N—H groups forms both an intra- and an inter­molecular N—H⋯O hydrogen bond; the other N—H group does not form any hydrogen bonds. In the crystal, pairs of the inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884485/ /pubmed/24426986 http://dx.doi.org/10.1107/S1600536813021892 Text en © Gul et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gul, Rukhsana
Khan, Azim
Badshah, Amin
Tahir, M. Nawaz
2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title_full 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title_fullStr 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title_full_unstemmed 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title_short 2-(3-Chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
title_sort 2-(3-chloro­benzo­yl)-3-(3,4-di­chloro­phen­yl)-1-(4-ferrocenylphen­yl)guanidine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884485/
https://www.ncbi.nlm.nih.gov/pubmed/24426986
http://dx.doi.org/10.1107/S1600536813021892
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