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2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine
In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclopentadienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and th...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884485/ https://www.ncbi.nlm.nih.gov/pubmed/24426986 http://dx.doi.org/10.1107/S1600536813021892 |
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author | Gul, Rukhsana Khan, Azim Badshah, Amin Tahir, M. Nawaz |
author_facet | Gul, Rukhsana Khan, Azim Badshah, Amin Tahir, M. Nawaz |
author_sort | Gul, Rukhsana |
collection | PubMed |
description | In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclopentadienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and the guanidine group is 64.8 (2)°. One of the N—H groups forms both an intra- and an intermolecular N—H⋯O hydrogen bond; the other N—H group does not form any hydrogen bonds. In the crystal, pairs of the intermolecular N—H⋯O hydrogen bonds link the molecules into inversion dimers. |
format | Online Article Text |
id | pubmed-3884485 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844852014-01-14 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine Gul, Rukhsana Khan, Azim Badshah, Amin Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(25)H(17)Cl(3)N(3)O)], the isolated cyclopentadienyl (Cp) ring is disordered over two set of sites in a 0.577 (8):0.423 (8) ratio. The dihedral angle between the other Cp ring and its attached benzene ring is 13.6 (3)°, and that between the benzene ring and the guanidine group is 64.8 (2)°. One of the N—H groups forms both an intra- and an intermolecular N—H⋯O hydrogen bond; the other N—H group does not form any hydrogen bonds. In the crystal, pairs of the intermolecular N—H⋯O hydrogen bonds link the molecules into inversion dimers. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884485/ /pubmed/24426986 http://dx.doi.org/10.1107/S1600536813021892 Text en © Gul et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gul, Rukhsana Khan, Azim Badshah, Amin Tahir, M. Nawaz 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title | 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title_full | 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title_fullStr | 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title_full_unstemmed | 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title_short | 2-(3-Chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
title_sort | 2-(3-chlorobenzoyl)-3-(3,4-dichlorophenyl)-1-(4-ferrocenylphenyl)guanidine |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884485/ https://www.ncbi.nlm.nih.gov/pubmed/24426986 http://dx.doi.org/10.1107/S1600536813021892 |
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