{[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium

The asymmetric unit of title salt co-crystal, [K(C(9)H(11)N(2)S(2))(C(12)H(24)O(6))], comprises a K(+) cation, an (−)S(2)CN(Et)py anion and a 18-crown-6 mol­ecule. Substantial delocalization of π-electron density is evident in the di­thio­carbamate anion, as indicated by the equivalent C—S bond leng...

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Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884488/
https://www.ncbi.nlm.nih.gov/pubmed/24426981
http://dx.doi.org/10.1107/S1600536813021569
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author Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of title salt co-crystal, [K(C(9)H(11)N(2)S(2))(C(12)H(24)O(6))], comprises a K(+) cation, an (−)S(2)CN(Et)py anion and a 18-crown-6 mol­ecule. Substantial delocalization of π-electron density is evident in the di­thio­carbamate anion, as indicated by the equivalent C—S bond lengths. The K(+) cation sits within an O(6)S(2) donor set lying 0.7506 (6) Å out of the least-squares plane through the six O atoms (r.m.s. deviation = 0.1766 Å) of the 18-crown-6 mol­ecule with the two S atoms being on one side of this plane. Supra­molecular layers in the bc plane, sustained by C—H⋯O and C—H⋯π inter­actions, feature in the crystal packing.
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spelling pubmed-38844882014-01-14 {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium Arman, Hadi D. Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title salt co-crystal, [K(C(9)H(11)N(2)S(2))(C(12)H(24)O(6))], comprises a K(+) cation, an (−)S(2)CN(Et)py anion and a 18-crown-6 mol­ecule. Substantial delocalization of π-electron density is evident in the di­thio­carbamate anion, as indicated by the equivalent C—S bond lengths. The K(+) cation sits within an O(6)S(2) donor set lying 0.7506 (6) Å out of the least-squares plane through the six O atoms (r.m.s. deviation = 0.1766 Å) of the 18-crown-6 mol­ecule with the two S atoms being on one side of this plane. Supra­molecular layers in the bc plane, sustained by C—H⋯O and C—H⋯π inter­actions, feature in the crystal packing. International Union of Crystallography 2013-08-07 /pmc/articles/PMC3884488/ /pubmed/24426981 http://dx.doi.org/10.1107/S1600536813021569 Text en © Arman et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
{[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title_full {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title_fullStr {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title_full_unstemmed {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title_short {[Eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) S,S′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) O)potassium
title_sort {[eth­yl(pyridin-4-ylmeth­yl)carbamo­thio­yl]sulfanido-κ(2) s,s′}(1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-κ(6) o)potassium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884488/
https://www.ncbi.nlm.nih.gov/pubmed/24426981
http://dx.doi.org/10.1107/S1600536813021569
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AT poplaukhinpavel ethylpyridin4ylmethylcarbamothioylsulfanidok2ss147101316hexaoxacyclooctadecanek6opotassium
AT tiekinkedwardrt ethylpyridin4ylmethylcarbamothioylsulfanidok2ss147101316hexaoxacyclooctadecanek6opotassium

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