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2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide

The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent mol­ecules having very similar geometries. The main N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecu...

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Detalles Bibliográficos
Autores principales: Bunev, Alexander S., Sklyuev, Prokofij V., Ostapenko, Gennady I., Purygin, Petr P., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884489/
https://www.ncbi.nlm.nih.gov/pubmed/24427094
http://dx.doi.org/10.1107/S1600536813023313
Descripción
Sumario:The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent mol­ecules having very similar geometries. The main N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecules). The adamantyl substituent occupies the gauche position relative to the C—N bond of the acetamide moiety [the corresponding N–C–C–C dihedral angles are −100.3 (3) and −96.5 (3)° for the two independent mol­ecules]. In the crystal, the two independent mol­ecules form a dimer via a pair of N—H⋯N hydrogen bonds. The dimers are further linked by C—H⋯O hydrogen bonds and attractive S⋯S [3.622 (2) Å] inter­actions into ribbons along [100].