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2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide

The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent mol­ecules having very similar geometries. The main N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecu...

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Autores principales: Bunev, Alexander S., Sklyuev, Prokofij V., Ostapenko, Gennady I., Purygin, Petr P., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884489/
https://www.ncbi.nlm.nih.gov/pubmed/24427094
http://dx.doi.org/10.1107/S1600536813023313
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author Bunev, Alexander S.
Sklyuev, Prokofij V.
Ostapenko, Gennady I.
Purygin, Petr P.
Khrustalev, Victor N.
author_facet Bunev, Alexander S.
Sklyuev, Prokofij V.
Ostapenko, Gennady I.
Purygin, Petr P.
Khrustalev, Victor N.
author_sort Bunev, Alexander S.
collection PubMed
description The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent mol­ecules having very similar geometries. The main N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecules). The adamantyl substituent occupies the gauche position relative to the C—N bond of the acetamide moiety [the corresponding N–C–C–C dihedral angles are −100.3 (3) and −96.5 (3)° for the two independent mol­ecules]. In the crystal, the two independent mol­ecules form a dimer via a pair of N—H⋯N hydrogen bonds. The dimers are further linked by C—H⋯O hydrogen bonds and attractive S⋯S [3.622 (2) Å] inter­actions into ribbons along [100].
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spelling pubmed-38844892014-01-14 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide Bunev, Alexander S. Sklyuev, Prokofij V. Ostapenko, Gennady I. Purygin, Petr P. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent mol­ecules having very similar geometries. The main N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecules). The adamantyl substituent occupies the gauche position relative to the C—N bond of the acetamide moiety [the corresponding N–C–C–C dihedral angles are −100.3 (3) and −96.5 (3)° for the two independent mol­ecules]. In the crystal, the two independent mol­ecules form a dimer via a pair of N—H⋯N hydrogen bonds. The dimers are further linked by C—H⋯O hydrogen bonds and attractive S⋯S [3.622 (2) Å] inter­actions into ribbons along [100]. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884489/ /pubmed/24427094 http://dx.doi.org/10.1107/S1600536813023313 Text en © Bunev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bunev, Alexander S.
Sklyuev, Prokofij V.
Ostapenko, Gennady I.
Purygin, Petr P.
Khrustalev, Victor N.
2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title_full 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title_fullStr 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title_full_unstemmed 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title_short 2-(Adamantan-1-yl)-N-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
title_sort 2-(adamantan-1-yl)-n-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884489/
https://www.ncbi.nlm.nih.gov/pubmed/24427094
http://dx.doi.org/10.1107/S1600536813023313
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