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2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide
The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent molecules having very similar geometries. The main N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecu...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884489/ https://www.ncbi.nlm.nih.gov/pubmed/24427094 http://dx.doi.org/10.1107/S1600536813023313 |
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author | Bunev, Alexander S. Sklyuev, Prokofij V. Ostapenko, Gennady I. Purygin, Petr P. Khrustalev, Victor N. |
author_facet | Bunev, Alexander S. Sklyuev, Prokofij V. Ostapenko, Gennady I. Purygin, Petr P. Khrustalev, Victor N. |
author_sort | Bunev, Alexander S. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent molecules having very similar geometries. The main N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecules). The adamantyl substituent occupies the gauche position relative to the C—N bond of the acetamide moiety [the corresponding N–C–C–C dihedral angles are −100.3 (3) and −96.5 (3)° for the two independent molecules]. In the crystal, the two independent molecules form a dimer via a pair of N—H⋯N hydrogen bonds. The dimers are further linked by C—H⋯O hydrogen bonds and attractive S⋯S [3.622 (2) Å] interactions into ribbons along [100]. |
format | Online Article Text |
id | pubmed-3884489 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844892014-01-14 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide Bunev, Alexander S. Sklyuev, Prokofij V. Ostapenko, Gennady I. Purygin, Petr P. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(24)N(2)O(2)S, contains two independent molecules having very similar geometries. The main N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide moiety adopts an almost planar structure (r.m.s. deviations of 0.091 and 0.051 Å for the two independent molecules). The adamantyl substituent occupies the gauche position relative to the C—N bond of the acetamide moiety [the corresponding N–C–C–C dihedral angles are −100.3 (3) and −96.5 (3)° for the two independent molecules]. In the crystal, the two independent molecules form a dimer via a pair of N—H⋯N hydrogen bonds. The dimers are further linked by C—H⋯O hydrogen bonds and attractive S⋯S [3.622 (2) Å] interactions into ribbons along [100]. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884489/ /pubmed/24427094 http://dx.doi.org/10.1107/S1600536813023313 Text en © Bunev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bunev, Alexander S. Sklyuev, Prokofij V. Ostapenko, Gennady I. Purygin, Petr P. Khrustalev, Victor N. 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title | 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title_full | 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title_fullStr | 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title_full_unstemmed | 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title_short | 2-(Adamantan-1-yl)-N-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
title_sort | 2-(adamantan-1-yl)-n-(6-methoxy-1,3-benzothiazol-2-yl)acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884489/ https://www.ncbi.nlm.nih.gov/pubmed/24427094 http://dx.doi.org/10.1107/S1600536813023313 |
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