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Lacinilene C 7-methyl ether

The title compound, C(16)H(20)O(3) [systematic name: 1-hy­droxy-7-meth­oxy-1,6-dimethyl-4-(propan-2-yl)naphthalen-2(1H)-one], is a sesquiterpene isolated from foliar tissues of the cotton plant and is of inter­est with respect to its anti­bacterial properties. Its phenyl ring is ideally planar, and...

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Detalles Bibliográficos
Autores principales: Uzbekov, Vyacheslav V., Talipov, Samat A., Ibragimov, Bakhtiyar T., Stipanovic, Robert D., Bell, Alois A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884496/
https://www.ncbi.nlm.nih.gov/pubmed/24427033
http://dx.doi.org/10.1107/S1600536813021430
Descripción
Sumario:The title compound, C(16)H(20)O(3) [systematic name: 1-hy­droxy-7-meth­oxy-1,6-dimethyl-4-(propan-2-yl)naphthalen-2(1H)-one], is a sesquiterpene isolated from foliar tissues of the cotton plant and is of inter­est with respect to its anti­bacterial properties. Its phenyl ring is ideally planar, and the maximum of deviation in the second ring is 0.386 (3) Å. The hy­droxy group and the methyl group are oriented in an equatorial fashion and axial, respectively, to the second ring. In the crystal, inversion dimers are formed through pairs of O—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds link the dimers into columns along the c axis. These columns form a crystal structure with a crystal packing factor of 0.66.