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Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)

The title compound, C(23)H(26)O(6)S(2) was synthesized by esterification of tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene­sulfonyl chloride. The mol­ecule has symmetry 2 and is situated on site 4e. The C—C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably long...

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Detalles Bibliográficos
Autores principales: Ioannou, Savvas, Moushi, Eleni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884498/
https://www.ncbi.nlm.nih.gov/pubmed/24427087
http://dx.doi.org/10.1107/S1600536813023234
Descripción
Sumario:The title compound, C(23)H(26)O(6)S(2) was synthesized by esterification of tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene­sulfonyl chloride. The mol­ecule has symmetry 2 and is situated on site 4e. The C—C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably longer than other C—C bonds in the mol­ecule. There are C—H⋯O inter­actions present in the structure. As a consequence, the packing of the molecule (viewed along [100]) appears as chains where the molecules run parallel, but each chain has the opposite direction to the neighboring ones.