Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)

The title compound, C(23)H(26)O(6)S(2) was synthesized by esterification of tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene­sulfonyl chloride. The mol­ecule has symmetry 2 and is situated on site 4e. The C—C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably long...

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Detalles Bibliográficos
Autores principales: Ioannou, Savvas, Moushi, Eleni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884498/
https://www.ncbi.nlm.nih.gov/pubmed/24427087
http://dx.doi.org/10.1107/S1600536813023234
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author Ioannou, Savvas
Moushi, Eleni
author_facet Ioannou, Savvas
Moushi, Eleni
author_sort Ioannou, Savvas
collection PubMed
description The title compound, C(23)H(26)O(6)S(2) was synthesized by esterification of tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene­sulfonyl chloride. The mol­ecule has symmetry 2 and is situated on site 4e. The C—C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably longer than other C—C bonds in the mol­ecule. There are C—H⋯O inter­actions present in the structure. As a consequence, the packing of the molecule (viewed along [100]) appears as chains where the molecules run parallel, but each chain has the opposite direction to the neighboring ones.
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spelling pubmed-38844982014-01-14 Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate) Ioannou, Savvas Moushi, Eleni Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(26)O(6)S(2) was synthesized by esterification of tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene­sulfonyl chloride. The mol­ecule has symmetry 2 and is situated on site 4e. The C—C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably longer than other C—C bonds in the mol­ecule. There are C—H⋯O inter­actions present in the structure. As a consequence, the packing of the molecule (viewed along [100]) appears as chains where the molecules run parallel, but each chain has the opposite direction to the neighboring ones. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884498/ /pubmed/24427087 http://dx.doi.org/10.1107/S1600536813023234 Text en © Ioannou and Moushi 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ioannou, Savvas
Moushi, Eleni
Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title_full Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title_fullStr Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title_full_unstemmed Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title_short Tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
title_sort tri­cyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(4-methyl­benzene­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884498/
https://www.ncbi.nlm.nih.gov/pubmed/24427087
http://dx.doi.org/10.1107/S1600536813023234
work_keys_str_mv AT ioannousavvas tricyclo331037nonane37diylbis4methylbenzenesulfonate
AT moushieleni tricyclo331037nonane37diylbis4methylbenzenesulfonate

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