Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc

The colourless title complex, [Zn(2)(C(10)H(11)O(5))(4)(C(2)H(6)OS)(2)], crystallizes with one half-mol­ecule in the asymmetric unit, the other half of the mol­ecule being generated by a crystallographic inversion center. The structure shows a μ(2)-O:O′-bridging mode of the four 3,4,5-tri­meth­oxy­b...

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Detalles Bibliográficos
Autores principales: Deutsch, Diana, Zevaco, Thomas, Walter, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884499/
https://www.ncbi.nlm.nih.gov/pubmed/24427007
http://dx.doi.org/10.1107/S1600536813023118
Descripción
Sumario:The colourless title complex, [Zn(2)(C(10)H(11)O(5))(4)(C(2)H(6)OS)(2)], crystallizes with one half-mol­ecule in the asymmetric unit, the other half of the mol­ecule being generated by a crystallographic inversion center. The structure shows a μ(2)-O:O′-bridging mode of the four 3,4,5-tri­meth­oxy­benzoate ligands finally stabilizing the two Zn(II) atoms in the dinuclear complex in a distorted square-pyramidal environment. The fifth coord­in­ation site in the apical position of the pyramid is occupied by a coordinating dimethyl sulfoxide solvent mol­ecule equally disordered over two positions.

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