Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc

The colourless title complex, [Zn(2)(C(10)H(11)O(5))(4)(C(2)H(6)OS)(2)], crystallizes with one half-mol­ecule in the asymmetric unit, the other half of the mol­ecule being generated by a crystallographic inversion center. The structure shows a μ(2)-O:O′-bridging mode of the four 3,4,5-tri­meth­oxy­b...

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Detalles Bibliográficos
Autores principales: Deutsch, Diana, Zevaco, Thomas, Walter, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884499/
https://www.ncbi.nlm.nih.gov/pubmed/24427007
http://dx.doi.org/10.1107/S1600536813023118
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author Deutsch, Diana
Zevaco, Thomas
Walter, Olaf
author_facet Deutsch, Diana
Zevaco, Thomas
Walter, Olaf
author_sort Deutsch, Diana
collection PubMed
description The colourless title complex, [Zn(2)(C(10)H(11)O(5))(4)(C(2)H(6)OS)(2)], crystallizes with one half-mol­ecule in the asymmetric unit, the other half of the mol­ecule being generated by a crystallographic inversion center. The structure shows a μ(2)-O:O′-bridging mode of the four 3,4,5-tri­meth­oxy­benzoate ligands finally stabilizing the two Zn(II) atoms in the dinuclear complex in a distorted square-pyramidal environment. The fifth coord­in­ation site in the apical position of the pyramid is occupied by a coordinating dimethyl sulfoxide solvent mol­ecule equally disordered over two positions.
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spelling pubmed-38844992014-01-14 Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc Deutsch, Diana Zevaco, Thomas Walter, Olaf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The colourless title complex, [Zn(2)(C(10)H(11)O(5))(4)(C(2)H(6)OS)(2)], crystallizes with one half-mol­ecule in the asymmetric unit, the other half of the mol­ecule being generated by a crystallographic inversion center. The structure shows a μ(2)-O:O′-bridging mode of the four 3,4,5-tri­meth­oxy­benzoate ligands finally stabilizing the two Zn(II) atoms in the dinuclear complex in a distorted square-pyramidal environment. The fifth coord­in­ation site in the apical position of the pyramid is occupied by a coordinating dimethyl sulfoxide solvent mol­ecule equally disordered over two positions. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884499/ /pubmed/24427007 http://dx.doi.org/10.1107/S1600536813023118 Text en © Deutsch et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deutsch, Diana
Zevaco, Thomas
Walter, Olaf
Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title_full Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title_fullStr Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title_full_unstemmed Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title_short Bis(dimethyl sulfoxide-κO)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) O:O′)dizinc
title_sort bis(dimethyl sulfoxide-κo)tetra­kis­(μ(2)-3,4,5-tri­meth­oxy­benzoato-κ(2) o:o′)dizinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884499/
https://www.ncbi.nlm.nih.gov/pubmed/24427007
http://dx.doi.org/10.1107/S1600536813023118
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AT zevacothomas bisdimethylsulfoxidekotetrakism2345trimethoxybenzoatok2oodizinc
AT walterolaf bisdimethylsulfoxidekotetrakism2345trimethoxybenzoatok2oodizinc

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