2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid

The asymmetric unit of the title compound, C(11)H(11)NO(4), contains two mol­ecules, A and B, with different conformations: in mol­ecule A, the norborne and carb­oxy­lic acid groups lie to the same side of the heterocycle, whereas in a mol­ecule B, they lie on opposite sides. In the crystal, the A m...

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Autores principales: Akkurt, Mehmet, Jarrahpour, Aliasghar, Shirvani, Pouria, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884503/
https://www.ncbi.nlm.nih.gov/pubmed/24427042
http://dx.doi.org/10.1107/S1600536813021764
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author Akkurt, Mehmet
Jarrahpour, Aliasghar
Shirvani, Pouria
Tahir, Muhammad Nawaz
author_facet Akkurt, Mehmet
Jarrahpour, Aliasghar
Shirvani, Pouria
Tahir, Muhammad Nawaz
author_sort Akkurt, Mehmet
collection PubMed
description The asymmetric unit of the title compound, C(11)H(11)NO(4), contains two mol­ecules, A and B, with different conformations: in mol­ecule A, the norborne and carb­oxy­lic acid groups lie to the same side of the heterocycle, whereas in a mol­ecule B, they lie on opposite sides. In the crystal, the A mol­ecules form R (2) (2)(8) carb­oxy­lic acid inversion dimers, linked by pairs of O—H⋯O hydrogen bonds. The B mol­ecules link to one of the ketone O atoms of the A mol­ecule by an O—H⋯O inter­action, resulting in tetra­mers (two A and two B mol­ecules). The tetra­mers are linked by weak C—H⋯O inter­actions, generating a three-dimensional network.
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spelling pubmed-38845032014-01-14 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid Akkurt, Mehmet Jarrahpour, Aliasghar Shirvani, Pouria Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(11)NO(4), contains two mol­ecules, A and B, with different conformations: in mol­ecule A, the norborne and carb­oxy­lic acid groups lie to the same side of the heterocycle, whereas in a mol­ecule B, they lie on opposite sides. In the crystal, the A mol­ecules form R (2) (2)(8) carb­oxy­lic acid inversion dimers, linked by pairs of O—H⋯O hydrogen bonds. The B mol­ecules link to one of the ketone O atoms of the A mol­ecule by an O—H⋯O inter­action, resulting in tetra­mers (two A and two B mol­ecules). The tetra­mers are linked by weak C—H⋯O inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884503/ /pubmed/24427042 http://dx.doi.org/10.1107/S1600536813021764 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Jarrahpour, Aliasghar
Shirvani, Pouria
Tahir, Muhammad Nawaz
2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title_full 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title_fullStr 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title_full_unstemmed 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title_short 2-(3,5-Dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
title_sort 2-(3,5-dioxo-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-en-4-yl)acetic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884503/
https://www.ncbi.nlm.nih.gov/pubmed/24427042
http://dx.doi.org/10.1107/S1600536813021764
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