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catena-Poly[[[2-(1,3-thiazol-4-yl)-1H-benzimidazole]manganese(II)]-μ-oxalato]
In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octahedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884504/ https://www.ncbi.nlm.nih.gov/pubmed/24427009 http://dx.doi.org/10.1107/S1600536813023428 |
Sumario: | In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octahedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the Mn(II) cations into a polymeric chain running along [101]. The thiazole ring is approximately coplanar with the benzimidazole ring system [dihedral angle = 4.19 (9)°]. In the crystal, classical N—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the polymeric chains into a three-dimensional supramolecular architecture. |
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