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catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]

In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octa­hedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the...

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Detalles Bibliográficos
Autores principales: Liang, Peng, Huang, Li-Ning, Yin, Xian-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884504/
https://www.ncbi.nlm.nih.gov/pubmed/24427009
http://dx.doi.org/10.1107/S1600536813023428
Descripción
Sumario:In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octa­hedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the Mn(II) cations into a polymeric chain running along [101]. The thia­zole ring is approximately coplanar with the benzimidazole ring system [dihedral angle = 4.19 (9)°]. In the crystal, classical N—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the polymeric chains into a three-dimensional supra­molecular architecture.