catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]

In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octa­hedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the...

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Detalles Bibliográficos
Autores principales: Liang, Peng, Huang, Li-Ning, Yin, Xian-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884504/
https://www.ncbi.nlm.nih.gov/pubmed/24427009
http://dx.doi.org/10.1107/S1600536813023428
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author Liang, Peng
Huang, Li-Ning
Yin, Xian-Hong
author_facet Liang, Peng
Huang, Li-Ning
Yin, Xian-Hong
author_sort Liang, Peng
collection PubMed
description In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octa­hedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the Mn(II) cations into a polymeric chain running along [101]. The thia­zole ring is approximately coplanar with the benzimidazole ring system [dihedral angle = 4.19 (9)°]. In the crystal, classical N—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the polymeric chains into a three-dimensional supra­molecular architecture.
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spelling pubmed-38845042014-01-14 catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato] Liang, Peng Huang, Li-Ning Yin, Xian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(2)O(4))(C(10)H(7)N(3)S)](n), the Mn(II) cation is chelated by one 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand and two oxalate anions in a distorted N(2)O(4) octa­hedral geometry. Two independent oxalate anions are located on individual inversion centers and bridge the Mn(II) cations into a polymeric chain running along [101]. The thia­zole ring is approximately coplanar with the benzimidazole ring system [dihedral angle = 4.19 (9)°]. In the crystal, classical N—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the polymeric chains into a three-dimensional supra­molecular architecture. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884504/ /pubmed/24427009 http://dx.doi.org/10.1107/S1600536813023428 Text en © Liang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Peng
Huang, Li-Ning
Yin, Xian-Hong
catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title_full catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title_fullStr catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title_full_unstemmed catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title_short catena-Poly[[[2-(1,3-thia­zol-4-yl)-1H-benzimidazole]­manganese(II)]-μ-oxalato]
title_sort catena-poly[[[2-(1,3-thia­zol-4-yl)-1h-benzimidazole]­manganese(ii)]-μ-oxalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884504/
https://www.ncbi.nlm.nih.gov/pubmed/24427009
http://dx.doi.org/10.1107/S1600536813023428
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