6-Amino-2-(pivaloyl­amino)­pyridinium benzoate

In the crystal structure of the title salt, C(10)H(16)N(3)O(+)·C(7)H(5)O(2) (−), the cations and anions are linked to each other via N—H⋯O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features C—H⋯O and π–π stacking inter­actions, which assemble the chains...

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Detalles Bibliográficos
Autores principales: Chęcińska, Lilianna, Ośmiałowski, Borys, Valkonen, Arto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884507/
https://www.ncbi.nlm.nih.gov/pubmed/24427104
http://dx.doi.org/10.1107/S1600536813023787
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author Chęcińska, Lilianna
Ośmiałowski, Borys
Valkonen, Arto
author_facet Chęcińska, Lilianna
Ośmiałowski, Borys
Valkonen, Arto
author_sort Chęcińska, Lilianna
collection PubMed
description In the crystal structure of the title salt, C(10)H(16)N(3)O(+)·C(7)H(5)O(2) (−), the cations and anions are linked to each other via N—H⋯O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features C—H⋯O and π–π stacking inter­actions, which assemble the chains into supra­molecular layers parallel to (100). The π–π stacking inter­actions are observed between the pyridine rings of inversion-related cations with a centroid–centroid distance of 3.867 (2) Å.
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spelling pubmed-38845072014-01-14 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate Chęcińska, Lilianna Ośmiałowski, Borys Valkonen, Arto Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(10)H(16)N(3)O(+)·C(7)H(5)O(2) (−), the cations and anions are linked to each other via N—H⋯O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features C—H⋯O and π–π stacking inter­actions, which assemble the chains into supra­molecular layers parallel to (100). The π–π stacking inter­actions are observed between the pyridine rings of inversion-related cations with a centroid–centroid distance of 3.867 (2) Å. International Union of Crystallography 2013-08-31 /pmc/articles/PMC3884507/ /pubmed/24427104 http://dx.doi.org/10.1107/S1600536813023787 Text en © Chęcińska et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chęcińska, Lilianna
Ośmiałowski, Borys
Valkonen, Arto
6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title_full 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title_fullStr 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title_full_unstemmed 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title_short 6-Amino-2-(pivaloyl­amino)­pyridinium benzoate
title_sort 6-amino-2-(pivaloyl­amino)­pyridinium benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884507/
https://www.ncbi.nlm.nih.gov/pubmed/24427104
http://dx.doi.org/10.1107/S1600536813023787
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AT osmiałowskiborys 6amino2pivaloylaminopyridiniumbenzoate
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