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Poly[μ-aqua-μ(5)-[2-(2,3,6-trichlorophenyl)acetato]-caesium]
In the structure of the title complex, [Cs(C(8)H(4)Cl(3)O(2))(H(2)O)](n), the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an or...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884976/ https://www.ncbi.nlm.nih.gov/pubmed/24454151 http://dx.doi.org/10.1107/S1600536813029395 |
Sumario: | In the structure of the title complex, [Cs(C(8)H(4)Cl(3)O(2))(H(2)O)](n), the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H⋯O hydrogen-bonding interactions. |
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