Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]

In the structure of the title complex, [Cs(C(8)H(4)Cl(3)O(2))(H(2)O)](n), the caesium salt of the commercial herbicide fenac [(2,3,6-tri­chloro­phen­yl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate inter­action involving a carboxyl­ate-O atom and an or...

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Detalles Bibliográficos
Autor principal: Smith, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884976/
https://www.ncbi.nlm.nih.gov/pubmed/24454151
http://dx.doi.org/10.1107/S1600536813029395
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author Smith, Graham
author_facet Smith, Graham
author_sort Smith, Graham
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description In the structure of the title complex, [Cs(C(8)H(4)Cl(3)O(2))(H(2)O)](n), the caesium salt of the commercial herbicide fenac [(2,3,6-tri­chloro­phen­yl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate inter­action involving a carboxyl­ate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxyl­ate-O atom and a bridging water mol­ecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxyl­ate O—H⋯O hy­dro­gen-bonding inter­actions.
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spelling pubmed-38849762014-01-17 Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium] Smith, Graham Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cs(C(8)H(4)Cl(3)O(2))(H(2)O)](n), the caesium salt of the commercial herbicide fenac [(2,3,6-tri­chloro­phen­yl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate inter­action involving a carboxyl­ate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxyl­ate-O atom and a bridging water mol­ecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxyl­ate O—H⋯O hy­dro­gen-bonding inter­actions. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3884976/ /pubmed/24454151 http://dx.doi.org/10.1107/S1600536813029395 Text en © Graham Smith 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Smith, Graham
Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title_full Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title_fullStr Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title_full_unstemmed Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title_short Poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
title_sort poly[μ-aqua-μ(5)-[2-(2,3,6-tri­chloro­phenyl)acetato]-caesium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884976/
https://www.ncbi.nlm.nih.gov/pubmed/24454151
http://dx.doi.org/10.1107/S1600536813029395
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