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Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis{μ (2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tricadmium
In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884977/ https://www.ncbi.nlm.nih.gov/pubmed/24454152 http://dx.doi.org/10.1107/S1600536813029413 |
Sumario: | In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN(2)C(3) ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C—H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane. |
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