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Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis{μ (2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tricadmium
In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884977/ https://www.ncbi.nlm.nih.gov/pubmed/24454152 http://dx.doi.org/10.1107/S1600536813029413 |
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author | Kubono, Koji Tani, Keita Yokoi, Kunihiko Shinmyozu, Teruo Goto, Kenta |
author_facet | Kubono, Koji Tani, Keita Yokoi, Kunihiko Shinmyozu, Teruo Goto, Kenta |
author_sort | Kubono, Koji |
collection | PubMed |
description | In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN(2)C(3) ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C—H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3884977 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38849772014-01-17 Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis{μ (2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tricadmium Kubono, Koji Tani, Keita Yokoi, Kunihiko Shinmyozu, Teruo Goto, Kenta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octahedral coordination geometry formed by four O atoms from two bidentate/tetradentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with the tetradentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN(2)C(3) ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C—H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supramolecular network structure lying parallel to the ab plane. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3884977/ /pubmed/24454152 http://dx.doi.org/10.1107/S1600536813029413 Text en © Kubono et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kubono, Koji Tani, Keita Yokoi, Kunihiko Shinmyozu, Teruo Goto, Kenta Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis{μ (2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tricadmium |
title | Di-μ
(2)-acetato-1:2κ
(2)
O:O′;2:3κ
(2)
O:O′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
O,N,N′,O′:O,O′;2:3κ
(6)
O,O′:O,N,N′,O′-tricadmium |
title_full | Di-μ
(2)-acetato-1:2κ
(2)
O:O′;2:3κ
(2)
O:O′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
O,N,N′,O′:O,O′;2:3κ
(6)
O,O′:O,N,N′,O′-tricadmium |
title_fullStr | Di-μ
(2)-acetato-1:2κ
(2)
O:O′;2:3κ
(2)
O:O′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
O,N,N′,O′:O,O′;2:3κ
(6)
O,O′:O,N,N′,O′-tricadmium |
title_full_unstemmed | Di-μ
(2)-acetato-1:2κ
(2)
O:O′;2:3κ
(2)
O:O′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
O,N,N′,O′:O,O′;2:3κ
(6)
O,O′:O,N,N′,O′-tricadmium |
title_short | Di-μ
(2)-acetato-1:2κ
(2)
O:O′;2:3κ
(2)
O:O′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
O,N,N′,O′:O,O′;2:3κ
(6)
O,O′:O,N,N′,O′-tricadmium |
title_sort | di-μ
(2)-acetato-1:2κ
(2)
o:o′;2:3κ
(2)
o:o′-bis{μ
(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ
(6)
o,n,n′,o′:o,o′;2:3κ
(6)
o,o′:o,n,n′,o′-tricadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884977/ https://www.ncbi.nlm.nih.gov/pubmed/24454152 http://dx.doi.org/10.1107/S1600536813029413 |
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