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Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium

In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination geometry formed by four O atoms from two bidentate/tetra­dentate Schiff base ligands and two O a...

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Autores principales: Kubono, Koji, Tani, Keita, Yokoi, Kunihiko, Shinmyozu, Teruo, Goto, Kenta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884977/
https://www.ncbi.nlm.nih.gov/pubmed/24454152
http://dx.doi.org/10.1107/S1600536813029413
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author Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
Shinmyozu, Teruo
Goto, Kenta
author_facet Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
Shinmyozu, Teruo
Goto, Kenta
author_sort Kubono, Koji
collection PubMed
description In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination geometry formed by four O atoms from two bidentate/tetra­dentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with the tetra­dentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN(2)C(3) ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C—H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supra­molecular network structure lying parallel to the ab plane.
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spelling pubmed-38849772014-01-17 Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium Kubono, Koji Tani, Keita Yokoi, Kunihiko Shinmyozu, Teruo Goto, Kenta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title linear homo-trinuclear complex, [Cd(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(C(2)H(3)O(2))(2)], the central Cd(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination geometry formed by four O atoms from two bidentate/tetra­dentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with the tetra­dentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN(2)C(3) ring adopts a chair conformation. The acetate-bridged Cd⋯Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C—H⋯O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supra­molecular network structure lying parallel to the ab plane. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3884977/ /pubmed/24454152 http://dx.doi.org/10.1107/S1600536813029413 Text en © Kubono et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
Shinmyozu, Teruo
Goto, Kenta
Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title_full Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title_fullStr Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title_full_unstemmed Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title_short Di-μ (2)-acetato-1:2κ (2) O:O′;2:3κ (2) O:O′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) O,N,N′,O′:O,O′;2:3κ (6) O,O′:O,N,N′,O′-tri­cadmium
title_sort di-μ (2)-acetato-1:2κ (2) o:o′;2:3κ (2) o:o′-bis­{μ (2)-4,4′-di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ (6) o,n,n′,o′:o,o′;2:3κ (6) o,o′:o,n,n′,o′-tri­cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884977/
https://www.ncbi.nlm.nih.gov/pubmed/24454152
http://dx.doi.org/10.1107/S1600536813029413
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