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{2,2′-[Ethane-1,2-diylbis(nitrilo­methan­yl­yl­idene)]diphenolato}(iso­propano­lato)aluminium di­chloro­methane hemisolvate

In the title compound, [Al(C(16)H(14)N(2)O(2))(C(3)H(7)O)]·0.5CH(2)Cl(2), the salen complex is monomeric and the dichlormethane solvent mol­ecule lies on a crystallographic twofold axis. The central Al atom is fivefold coordinated and possesses a square-based pyramidal environment. The Al—OAlk((i)pr...

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Detalles Bibliográficos
Autores principales: Zaitsev, Kirill V., Kuchuk, Ekaterina A., Karlov, Sergey S., Zaitseva, Galina S., Churakov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884978/
https://www.ncbi.nlm.nih.gov/pubmed/24454153
http://dx.doi.org/10.1107/S1600536813029644
Descripción
Sumario:In the title compound, [Al(C(16)H(14)N(2)O(2))(C(3)H(7)O)]·0.5CH(2)Cl(2), the salen complex is monomeric and the dichlormethane solvent mol­ecule lies on a crystallographic twofold axis. The central Al atom is fivefold coordinated and possesses a square-based pyramidal environment. The Al—OAlk((i)prop­yl) bond [1.7404 (14) Å] is much shorter than the Al—OAr(salen) bond lengths [1.7974 (15) and 1.8094 (14) Å]. The iso­propyl­oxo group forms an intra­molecular C—H⋯N hydrogen bond. In the crystal, the complex mol­ecules are linked by weak C—H⋯O inter­actions.