N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate

The asymmetric unit of the title compound, (C(6)H(18)N(2))[ZnCl(4)], consists of one tetra­chlorido­zincate anion and two half-N,N,N′N′-tetra­methyl­ethylenedi­ammonium cations. Each of the two di­ammonium cations is located about an inversion center and one of them is disordered over two sets of si...

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Autores principales: Akhtar, Muhammad, Fettouhi, Mohammed, Ahmed, Maqsood, Khan, Islam Ullah, Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884984/
https://www.ncbi.nlm.nih.gov/pubmed/24454159
http://dx.doi.org/10.1107/S1600536813029802
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author Akhtar, Muhammad
Fettouhi, Mohammed
Ahmed, Maqsood
Khan, Islam Ullah
Ahmad, Saeed
author_facet Akhtar, Muhammad
Fettouhi, Mohammed
Ahmed, Maqsood
Khan, Islam Ullah
Ahmad, Saeed
author_sort Akhtar, Muhammad
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(18)N(2))[ZnCl(4)], consists of one tetra­chlorido­zincate anion and two half-N,N,N′N′-tetra­methyl­ethylenedi­ammonium cations. Each of the two di­ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra­hedral coordination environment. The cations and anions are connected via N—H⋯Cl hydrogen bonds into chains extending along [0-11].
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spelling pubmed-38849842014-01-17 N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate Akhtar, Muhammad Fettouhi, Mohammed Ahmed, Maqsood Khan, Islam Ullah Ahmad, Saeed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(18)N(2))[ZnCl(4)], consists of one tetra­chlorido­zincate anion and two half-N,N,N′N′-tetra­methyl­ethylenedi­ammonium cations. Each of the two di­ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra­hedral coordination environment. The cations and anions are connected via N—H⋯Cl hydrogen bonds into chains extending along [0-11]. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3884984/ /pubmed/24454159 http://dx.doi.org/10.1107/S1600536813029802 Text en © Akhtar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akhtar, Muhammad
Fettouhi, Mohammed
Ahmed, Maqsood
Khan, Islam Ullah
Ahmad, Saeed
N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title_full N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title_fullStr N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title_full_unstemmed N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title_short N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
title_sort n,n,n′,n′-tetra­methyl­ethylene­diammonium tetra­chlorido­zincate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884984/
https://www.ncbi.nlm.nih.gov/pubmed/24454159
http://dx.doi.org/10.1107/S1600536813029802
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