Hexa-μ-acetato-1:2κ(4) O,O′;1:2κ(2) O:O;2:3κ(4) O,O′;2:3κ(2) O:O-bis­(4,4′-dimethyl-2,2′-bi­pyridine)-1κ(2) N,N′;3κ(2) N,N′-2-calcium-1,3-dizinc

In the centrosymmetric trinuclear Zn(II)⋯Ca(II)⋯Zn(II) title complex, [CaZn(2)(CH(3)COO)(6)(C(12)H(12)N(2))(2)], the Ca(II) ion lies on an inversion centre and is octa­hedrally coordinated by six acetate O atoms. The Zn(II) ion is coordinated by two N atoms from a bidentate di­methyl­bipyridine liga...

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Detalles Bibliográficos
Autores principales: Pramanik, Avijit, Fronczek, Frank R., Venkatraman, Ramaiyer, Hossain, Md. Alamgir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884985/
https://www.ncbi.nlm.nih.gov/pubmed/24454160
http://dx.doi.org/10.1107/S1600536813030122
Descripción
Sumario:In the centrosymmetric trinuclear Zn(II)⋯Ca(II)⋯Zn(II) title complex, [CaZn(2)(CH(3)COO)(6)(C(12)H(12)N(2))(2)], the Ca(II) ion lies on an inversion centre and is octa­hedrally coordinated by six acetate O atoms. The Zn(II) ion is coordinated by two N atoms from a bidentate di­methyl­bipyridine ligand and three O atoms from acetate ligands bridging to the Ca(II) ion, leading to a distorted square-pyramidal coordination sphere. The Zn⋯Ca distance is 3.4668 (5) Å.

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