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Hexa-μ-acetato-1:2κ(4) O,O′;1:2κ(2) O:O;2:3κ(4) O,O′;2:3κ(2) O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-2-calcium-1,3-dizinc
In the centrosymmetric trinuclear Zn(II)⋯Ca(II)⋯Zn(II) title complex, [CaZn(2)(CH(3)COO)(6)(C(12)H(12)N(2))(2)], the Ca(II) ion lies on an inversion centre and is octahedrally coordinated by six acetate O atoms. The Zn(II) ion is coordinated by two N atoms from a bidentate dimethylbipyridine liga...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884985/ https://www.ncbi.nlm.nih.gov/pubmed/24454160 http://dx.doi.org/10.1107/S1600536813030122 |
| _version_ | 1782298684438872064 |
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| author | Pramanik, Avijit Fronczek, Frank R. Venkatraman, Ramaiyer Hossain, Md. Alamgir |
| author_facet | Pramanik, Avijit Fronczek, Frank R. Venkatraman, Ramaiyer Hossain, Md. Alamgir |
| author_sort | Pramanik, Avijit |
| collection | PubMed |
| description | In the centrosymmetric trinuclear Zn(II)⋯Ca(II)⋯Zn(II) title complex, [CaZn(2)(CH(3)COO)(6)(C(12)H(12)N(2))(2)], the Ca(II) ion lies on an inversion centre and is octahedrally coordinated by six acetate O atoms. The Zn(II) ion is coordinated by two N atoms from a bidentate dimethylbipyridine ligand and three O atoms from acetate ligands bridging to the Ca(II) ion, leading to a distorted square-pyramidal coordination sphere. The Zn⋯Ca distance is 3.4668 (5) Å. |
| format | Online Article Text |
| id | pubmed-3884985 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38849852014-01-17 Hexa-μ-acetato-1:2κ(4) O,O′;1:2κ(2) O:O;2:3κ(4) O,O′;2:3κ(2) O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-2-calcium-1,3-dizinc Pramanik, Avijit Fronczek, Frank R. Venkatraman, Ramaiyer Hossain, Md. Alamgir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric trinuclear Zn(II)⋯Ca(II)⋯Zn(II) title complex, [CaZn(2)(CH(3)COO)(6)(C(12)H(12)N(2))(2)], the Ca(II) ion lies on an inversion centre and is octahedrally coordinated by six acetate O atoms. The Zn(II) ion is coordinated by two N atoms from a bidentate dimethylbipyridine ligand and three O atoms from acetate ligands bridging to the Ca(II) ion, leading to a distorted square-pyramidal coordination sphere. The Zn⋯Ca distance is 3.4668 (5) Å. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884985/ /pubmed/24454160 http://dx.doi.org/10.1107/S1600536813030122 Text en © Pramanik et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Pramanik, Avijit Fronczek, Frank R. Venkatraman, Ramaiyer Hossain, Md. Alamgir Hexa-μ-acetato-1:2κ(4) O,O′;1:2κ(2) O:O;2:3κ(4) O,O′;2:3κ(2) O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-2-calcium-1,3-dizinc |
| title | Hexa-μ-acetato-1:2κ(4)
O,O′;1:2κ(2)
O:O;2:3κ(4)
O,O′;2:3κ(2)
O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-2-calcium-1,3-dizinc |
| title_full | Hexa-μ-acetato-1:2κ(4)
O,O′;1:2κ(2)
O:O;2:3κ(4)
O,O′;2:3κ(2)
O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-2-calcium-1,3-dizinc |
| title_fullStr | Hexa-μ-acetato-1:2κ(4)
O,O′;1:2κ(2)
O:O;2:3κ(4)
O,O′;2:3κ(2)
O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-2-calcium-1,3-dizinc |
| title_full_unstemmed | Hexa-μ-acetato-1:2κ(4)
O,O′;1:2κ(2)
O:O;2:3κ(4)
O,O′;2:3κ(2)
O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-2-calcium-1,3-dizinc |
| title_short | Hexa-μ-acetato-1:2κ(4)
O,O′;1:2κ(2)
O:O;2:3κ(4)
O,O′;2:3κ(2)
O:O-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-2-calcium-1,3-dizinc |
| title_sort | hexa-μ-acetato-1:2κ(4)
o,o′;1:2κ(2)
o:o;2:3κ(4)
o,o′;2:3κ(2)
o:o-bis(4,4′-dimethyl-2,2′-bipyridine)-1κ(2)
n,n′;3κ(2)
n,n′-2-calcium-1,3-dizinc |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884985/ https://www.ncbi.nlm.nih.gov/pubmed/24454160 http://dx.doi.org/10.1107/S1600536813030122 |
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