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Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium

In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octa­hedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetra­zole ligands; the axial sites are occupied...

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Detalles Bibliográficos
Autores principales: Liang, Qian, Wang, Yulin, Zhao, Yan, Cao, Gaojuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884986/
https://www.ncbi.nlm.nih.gov/pubmed/24454161
http://dx.doi.org/10.1107/S1600536813030158
Descripción
Sumario:In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octa­hedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetra­zole ligands; the axial sites are occupied by two water mol­ecules, with longer Cd—O bond lengths. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O as well as O—H⋯O and O—H⋯N hydrogen bonds (some of which are bifurcated) link the complex mol­ecules into a three-dimensional network.