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Bis(5-amino-1H-tetrazole-κN (4))diaqua(oxalato-κ(2) O (1),O (2))cadmium
In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octahedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetrazole ligands; the axial sites are occupied...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884986/ https://www.ncbi.nlm.nih.gov/pubmed/24454161 http://dx.doi.org/10.1107/S1600536813030158 |
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author | Liang, Qian Wang, Yulin Zhao, Yan Cao, Gaojuan |
author_facet | Liang, Qian Wang, Yulin Zhao, Yan Cao, Gaojuan |
author_sort | Liang, Qian |
collection | PubMed |
description | In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octahedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetrazole ligands; the axial sites are occupied by two water molecules, with longer Cd—O bond lengths. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O as well as O—H⋯O and O—H⋯N hydrogen bonds (some of which are bifurcated) link the complex molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3884986 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38849862014-01-17 Bis(5-amino-1H-tetrazole-κN (4))diaqua(oxalato-κ(2) O (1),O (2))cadmium Liang, Qian Wang, Yulin Zhao, Yan Cao, Gaojuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octahedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetrazole ligands; the axial sites are occupied by two water molecules, with longer Cd—O bond lengths. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O as well as O—H⋯O and O—H⋯N hydrogen bonds (some of which are bifurcated) link the complex molecules into a three-dimensional network. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884986/ /pubmed/24454161 http://dx.doi.org/10.1107/S1600536813030158 Text en © Liang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liang, Qian Wang, Yulin Zhao, Yan Cao, Gaojuan Bis(5-amino-1H-tetrazole-κN (4))diaqua(oxalato-κ(2) O (1),O (2))cadmium |
title | Bis(5-amino-1H-tetrazole-κN
(4))diaqua(oxalato-κ(2)
O
(1),O
(2))cadmium |
title_full | Bis(5-amino-1H-tetrazole-κN
(4))diaqua(oxalato-κ(2)
O
(1),O
(2))cadmium |
title_fullStr | Bis(5-amino-1H-tetrazole-κN
(4))diaqua(oxalato-κ(2)
O
(1),O
(2))cadmium |
title_full_unstemmed | Bis(5-amino-1H-tetrazole-κN
(4))diaqua(oxalato-κ(2)
O
(1),O
(2))cadmium |
title_short | Bis(5-amino-1H-tetrazole-κN
(4))diaqua(oxalato-κ(2)
O
(1),O
(2))cadmium |
title_sort | bis(5-amino-1h-tetrazole-κn
(4))diaqua(oxalato-κ(2)
o
(1),o
(2))cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884986/ https://www.ncbi.nlm.nih.gov/pubmed/24454161 http://dx.doi.org/10.1107/S1600536813030158 |
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