Cargando…

Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium

In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octa­hedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetra­zole ligands; the axial sites are occupied...

Descripción completa

Detalles Bibliográficos
Autores principales: Liang, Qian, Wang, Yulin, Zhao, Yan, Cao, Gaojuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884986/
https://www.ncbi.nlm.nih.gov/pubmed/24454161
http://dx.doi.org/10.1107/S1600536813030158
_version_ 1782298684669558784
author Liang, Qian
Wang, Yulin
Zhao, Yan
Cao, Gaojuan
author_facet Liang, Qian
Wang, Yulin
Zhao, Yan
Cao, Gaojuan
author_sort Liang, Qian
collection PubMed
description In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octa­hedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetra­zole ligands; the axial sites are occupied by two water mol­ecules, with longer Cd—O bond lengths. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O as well as O—H⋯O and O—H⋯N hydrogen bonds (some of which are bifurcated) link the complex mol­ecules into a three-dimensional network.
format Online
Article
Text
id pubmed-3884986
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38849862014-01-17 Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium Liang, Qian Wang, Yulin Zhao, Yan Cao, Gaojuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Cd(C(2)O(4))(CH(3)N(5))(2)(H(2)O)(2)], the Cd(II) ion exhibits a distorted octa­hedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetra­zole ligands; the axial sites are occupied by two water mol­ecules, with longer Cd—O bond lengths. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O as well as O—H⋯O and O—H⋯N hydrogen bonds (some of which are bifurcated) link the complex mol­ecules into a three-dimensional network. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884986/ /pubmed/24454161 http://dx.doi.org/10.1107/S1600536813030158 Text en © Liang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Qian
Wang, Yulin
Zhao, Yan
Cao, Gaojuan
Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title_full Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title_fullStr Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title_full_unstemmed Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title_short Bis(5-amino-1H-tetra­zole-κN (4))di­aqua­(oxalato-κ(2) O (1),O (2))cadmium
title_sort bis(5-amino-1h-tetra­zole-κn (4))di­aqua­(oxalato-κ(2) o (1),o (2))cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884986/
https://www.ncbi.nlm.nih.gov/pubmed/24454161
http://dx.doi.org/10.1107/S1600536813030158
work_keys_str_mv AT liangqian bis5amino1htetrazolekn4diaquaoxalatok2o1o2cadmium
AT wangyulin bis5amino1htetrazolekn4diaquaoxalatok2o1o2cadmium
AT zhaoyan bis5amino1htetrazolekn4diaquaoxalatok2o1o2cadmium
AT caogaojuan bis5amino1htetrazolekn4diaquaoxalatok2o1o2cadmium