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Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate

In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octa­hedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) ...

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Detalles Bibliográficos
Autores principales: Sahbani, Thameur, Smirani Sta, Wajda, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988/
https://www.ncbi.nlm.nih.gov/pubmed/24454163
http://dx.doi.org/10.1107/S1600536813030365
Descripción
Sumario:In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octa­hedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octa­hedron in the axial positions. Neighboring complex mol­ecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O(water)—H⋯O hydrogen bonds involving the non-coordinating water mol­ecules and C—H⋯O inter­actions connect these layers into a three-dimensional supra­molecular structure.