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Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate
In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) ...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988/ https://www.ncbi.nlm.nih.gov/pubmed/24454163 http://dx.doi.org/10.1107/S1600536813030365 |
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author | Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed |
author_facet | Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed |
author_sort | Sahbani, Thameur |
collection | PubMed |
description | In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octahedron in the axial positions. Neighboring complex molecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O(water)—H⋯O hydrogen bonds involving the non-coordinating water molecules and C—H⋯O interactions connect these layers into a three-dimensional supramolecular structure. |
format | Online Article Text |
id | pubmed-3884988 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38849882014-01-17 Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octahedron in the axial positions. Neighboring complex molecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O(water)—H⋯O hydrogen bonds involving the non-coordinating water molecules and C—H⋯O interactions connect these layers into a three-dimensional supramolecular structure. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884988/ /pubmed/24454163 http://dx.doi.org/10.1107/S1600536813030365 Text en © Sahbani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title_full | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title_fullStr | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title_full_unstemmed | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title_short | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
title_sort | tetraaquabis(piperazin-1-ium)cobalt(ii) bis(sulfate) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988/ https://www.ncbi.nlm.nih.gov/pubmed/24454163 http://dx.doi.org/10.1107/S1600536813030365 |
work_keys_str_mv | AT sahbanithameur tetraaquabispiperazin1iumcobaltiibissulfatedihydrate AT smiranistawajda tetraaquabispiperazin1iumcobaltiibissulfatedihydrate AT rzaiguimohamed tetraaquabispiperazin1iumcobaltiibissulfatedihydrate |