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Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate

In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octa­hedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) ...

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Detalles Bibliográficos
Autores principales: Sahbani, Thameur, Smirani Sta, Wajda, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988/
https://www.ncbi.nlm.nih.gov/pubmed/24454163
http://dx.doi.org/10.1107/S1600536813030365
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author Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
author_facet Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
author_sort Sahbani, Thameur
collection PubMed
description In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octa­hedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octa­hedron in the axial positions. Neighboring complex mol­ecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O(water)—H⋯O hydrogen bonds involving the non-coordinating water mol­ecules and C—H⋯O inter­actions connect these layers into a three-dimensional supra­molecular structure.
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spelling pubmed-38849882014-01-17 Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Co(C(4)H(11)N(2))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O, the Co(II) atom is coordinated in a distorted octa­hedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octa­hedron in the axial positions. Neighboring complex mol­ecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O(water)—H⋯O hydrogen bonds involving the non-coordinating water mol­ecules and C—H⋯O inter­actions connect these layers into a three-dimensional supra­molecular structure. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884988/ /pubmed/24454163 http://dx.doi.org/10.1107/S1600536813030365 Text en © Sahbani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title_full Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title_fullStr Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title_full_unstemmed Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title_short Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate
title_sort tetra­aqua­bis­(piperazin-1-ium)cobalt(ii) bis­(sulfate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988/
https://www.ncbi.nlm.nih.gov/pubmed/24454163
http://dx.doi.org/10.1107/S1600536813030365
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