(μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]

In the title compound, [Co(4)(C(5)H(5))(4)(μ(3)-CCH(2)SiMe(3))(μ(3)-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co—Co bond lengths in the Co(4) tetrahedron vary from...

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Detalles Bibliográficos
Autores principales: Haehnel, Martin, Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884989/
https://www.ncbi.nlm.nih.gov/pubmed/24454164
http://dx.doi.org/10.1107/S1600536813030432
Descripción
Sumario:In the title compound, [Co(4)(C(5)H(5))(4)(μ(3)-CCH(2)SiMe(3))(μ(3)-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co—Co bond lengths in the Co(4) tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η(5)-bonded to a cyclopentadienyl (Cp) anion.

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