(μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]

In the title compound, [Co(4)(C(5)H(5))(4)(μ(3)-CCH(2)SiMe(3))(μ(3)-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co—Co bond lengths in the Co(4) tetrahedron vary from...

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Detalles Bibliográficos
Autores principales: Haehnel, Martin, Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884989/
https://www.ncbi.nlm.nih.gov/pubmed/24454164
http://dx.doi.org/10.1107/S1600536813030432
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author Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
author_facet Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
author_sort Haehnel, Martin
collection PubMed
description In the title compound, [Co(4)(C(5)H(5))(4)(μ(3)-CCH(2)SiMe(3))(μ(3)-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co—Co bond lengths in the Co(4) tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η(5)-bonded to a cyclopentadienyl (Cp) anion.
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spelling pubmed-38849892014-01-17 (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)] Haehnel, Martin Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(4)(C(5)H(5))(4)(μ(3)-CCH(2)SiMe(3))(μ(3)-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co—Co bond lengths in the Co(4) tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η(5)-bonded to a cyclopentadienyl (Cp) anion. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3884989/ /pubmed/24454164 http://dx.doi.org/10.1107/S1600536813030432 Text en © Haehnel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
(μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title_full (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title_fullStr (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title_full_unstemmed (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title_short (μ(3)-Hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) C (1):C (1):C (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(II)]
title_sort (μ(3)-hydrido)[μ(3)-2-(tri­methyl­sil­yl)ethyl­idyne-κ(3) c (1):c (1):c (1)]tetra­kis­[(η(5)-cyclo­penta­dien­yl)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884989/
https://www.ncbi.nlm.nih.gov/pubmed/24454164
http://dx.doi.org/10.1107/S1600536813030432
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