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[meso-5,10,15,20-Tetrakis(3-methylthiophen-2-yl)porphyrinato-κ(4) N,N′,N′′,N′′′]nickel(II) benzene hemisolvate
In the title compound, [Ni(C(40)H(28)N(4)S(4))]·0.5C(6)H(6), the Ni(II) atom is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N(4) donor set and the pyrrole rings being in the range 16.24 (5)–22....
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884990/ https://www.ncbi.nlm.nih.gov/pubmed/24454165 http://dx.doi.org/10.1107/S1600536813030468 |