Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal

In the crystal structure of the title compound, [Mn(C(5)H(7)O(2))(2)(NCS)(C(5)H(5)N)], the Mn(3+) cation is coordin­ated by two acetyl­acetonate anions, one terminal thio­cyanate anion and one pyridine ligand within a slightly distorted octa­hedron. The asymmetric unit consists of half a complex mol...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884993/
https://www.ncbi.nlm.nih.gov/pubmed/24454168
http://dx.doi.org/10.1107/S1600536813030407
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author Suckert, Stefan
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description In the crystal structure of the title compound, [Mn(C(5)H(7)O(2))(2)(NCS)(C(5)H(5)N)], the Mn(3+) cation is coordin­ated by two acetyl­acetonate anions, one terminal thio­cyanate anion and one pyridine ligand within a slightly distorted octa­hedron. The asymmetric unit consists of half a complex mol­ecule with the Mn(3+) cation, the thio­cyanate anion and the pyridine ligand located on a mirror plane. The acetyl­acetonate anion is in a general position. The title compound was previously described [Stults et al. (1975 ▶). Inorg. Chem. 14, 722–730] but could only be obtained as a powder. Suitable crystals have now been obtained for a high-precision single-crystal structure determination.
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spelling pubmed-38849932014-01-17 Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(C(5)H(7)O(2))(2)(NCS)(C(5)H(5)N)], the Mn(3+) cation is coordin­ated by two acetyl­acetonate anions, one terminal thio­cyanate anion and one pyridine ligand within a slightly distorted octa­hedron. The asymmetric unit consists of half a complex mol­ecule with the Mn(3+) cation, the thio­cyanate anion and the pyridine ligand located on a mirror plane. The acetyl­acetonate anion is in a general position. The title compound was previously described [Stults et al. (1975 ▶). Inorg. Chem. 14, 722–730] but could only be obtained as a powder. Suitable crystals have now been obtained for a high-precision single-crystal structure determination. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3884993/ /pubmed/24454168 http://dx.doi.org/10.1107/S1600536813030407 Text en © Suckert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suckert, Stefan
Jess, Inke
Näther, Christian
Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title_full Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title_fullStr Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title_full_unstemmed Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title_short Bis(acetyl­acetonato-κ(2) O,O′)(pyridine-κN)(thio­cyanato-κN)manganese(III): a redetermination using data from a single crystal
title_sort bis(acetyl­acetonato-κ(2) o,o′)(pyridine-κn)(thio­cyanato-κn)manganese(iii): a redetermination using data from a single crystal
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884993/
https://www.ncbi.nlm.nih.gov/pubmed/24454168
http://dx.doi.org/10.1107/S1600536813030407
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AT natherchristian bisacetylacetonatok2oopyridineknthiocyanatoknmanganeseiiiaredeterminationusingdatafromasinglecrystal

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