[μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]

In the centrosymmetric dinuclear title complex, [Cu(2)(C(24)H(18)N(4)O(6))(C(5)H(5)N)(2)], the Cu(II) ions is tetra­coordinated by two O-atoms and one N-donor of the bridging terephthalo­hydra­zonate ligand and by one pyridine N atom, resulting in a nearly square-planar N(2)O(2) coordination geometr...

Descripción completa

Detalles Bibliográficos
Autores principales: Tong, Hai-Bin, Xiao, Zi-Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884994/
https://www.ncbi.nlm.nih.gov/pubmed/24454169
http://dx.doi.org/10.1107/S1600536813030286
_version_ 1782298686533926912
author Tong, Hai-Bin
Xiao, Zi-Jing
author_facet Tong, Hai-Bin
Xiao, Zi-Jing
author_sort Tong, Hai-Bin
collection PubMed
description In the centrosymmetric dinuclear title complex, [Cu(2)(C(24)H(18)N(4)O(6))(C(5)H(5)N)(2)], the Cu(II) ions is tetra­coordinated by two O-atoms and one N-donor of the bridging terephthalo­hydra­zonate ligand and by one pyridine N atom, resulting in a nearly square-planar N(2)O(2) coordination geometry with the Cu(II) ion 0.044 (2) Å out of the mean plane (r.m.s. deviation of 0.0675 Å) of the coordinating atoms.
format Online
Article
Text
id pubmed-3884994
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38849942014-01-17 [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)] Tong, Hai-Bin Xiao, Zi-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(C(24)H(18)N(4)O(6))(C(5)H(5)N)(2)], the Cu(II) ions is tetra­coordinated by two O-atoms and one N-donor of the bridging terephthalo­hydra­zonate ligand and by one pyridine N atom, resulting in a nearly square-planar N(2)O(2) coordination geometry with the Cu(II) ion 0.044 (2) Å out of the mean plane (r.m.s. deviation of 0.0675 Å) of the coordinating atoms. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3884994/ /pubmed/24454169 http://dx.doi.org/10.1107/S1600536813030286 Text en © Tong and Xiao 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tong, Hai-Bin
Xiao, Zi-Jing
[μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title_full [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title_fullStr [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title_full_unstemmed [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title_short [μ(2)-N (2),N (2′)-Bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(II)]
title_sort [μ(2)-n (2),n (2′)-bis(3-meth­oxy-2-oxido­benzyl­idene)benzene-1,3-dicarbo­hydrazi­dato]bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884994/
https://www.ncbi.nlm.nih.gov/pubmed/24454169
http://dx.doi.org/10.1107/S1600536813030286
work_keys_str_mv AT tonghaibin m2n2n2bis3methoxy2oxidobenzylidenebenzene13dicarbohydrazidatobispyridinecopperii
AT xiaozijing m2n2n2bis3methoxy2oxidobenzylidenebenzene13dicarbohydrazidatobispyridinecopperii

Ejemplares similares