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Chlorido(η(6)-N (2)-diphenylphosphanyl-N (1),N (1)-diisopropyl-4-methoxybenzamidine-κP)(triphenylphosphane-κP)ruthenium(II) trifluoromethansulfonate acetone disolvate
In the title compound, [RuCl(C(18)H(15)P)(C(26)H(31)N(2)OP)](CF(3)O(3)S)·2C(3)H(6)O, the Ru(II) ion is coordinated in a three-legged piano stool, half-sandwich-type geometry by a chlorido ligand, a triphenylphosphine and a tethered η(6)-(phenyl-p-O-methoxy) κ(1)-P N-diphenylphosphino N′-diisopr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884995/ https://www.ncbi.nlm.nih.gov/pubmed/24454170 http://dx.doi.org/10.1107/S1600536813029450 |
Sumario: | In the title compound, [RuCl(C(18)H(15)P)(C(26)H(31)N(2)OP)](CF(3)O(3)S)·2C(3)H(6)O, the Ru(II) ion is coordinated in a three-legged piano stool, half-sandwich-type geometry by a chlorido ligand, a triphenylphosphine and a tethered η(6)-(phenyl-p-O-methoxy) κ(1)-P N-diphenylphosphino N′-diisopropyl amidine ligand charge-balanced by a trifluormethansulfonate counter-anion. The η(6)-coordination mode of the arene incorporated into the structure was generated in situ after addition of methyl trifluoromethanesulfonate to the neutral η(5)-arene tethered precursor complex [RuCl(PPh(3))(η(5):κ(1)-OC(6)H(4)C(NiPr(2))=N-PPh(2))] in dichloromethane solution. |
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