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Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate

In the title organic–inorganic hybrid compound, (C(5)H(7)N(2))(2)[ReVW(4)O(19)]·7H(2)O, the Lindqvist-type polyoxido anion has crystallographically imposed mm2 symmetry and is built up by six MO(6) (M = W, V, Re) edge-sharing distorted octa­hedra. The Re and V atoms share the same crystallographic s...

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Detalles Bibliográficos
Autores principales: Maaloui, Ahlem, Toumi, Samah Akriche, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884996/
https://www.ncbi.nlm.nih.gov/pubmed/24454171
http://dx.doi.org/10.1107/S1600536813030687
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author Maaloui, Ahlem
Toumi, Samah Akriche
Rzaigui, Mohamed
author_facet Maaloui, Ahlem
Toumi, Samah Akriche
Rzaigui, Mohamed
author_sort Maaloui, Ahlem
collection PubMed
description In the title organic–inorganic hybrid compound, (C(5)H(7)N(2))(2)[ReVW(4)O(19)]·7H(2)O, the Lindqvist-type polyoxido anion has crystallographically imposed mm2 symmetry and is built up by six MO(6) (M = W, V, Re) edge-sharing distorted octa­hedra. The Re and V atoms share the same crystallographic site in a 0.5:0.5 ratio. The 4-amino­pyridinium cations lie on a mirror plane. Three of the four independent water O atoms in the asymmetric unit are located on a mirror plane whereas the remaining O atom has mm2 site symmetry. In the crystal, the cations, anions and water mol­ecules are linked into a three-dimensional network through O—H⋯O and N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-38849962014-01-17 Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate Maaloui, Ahlem Toumi, Samah Akriche Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title organic–inorganic hybrid compound, (C(5)H(7)N(2))(2)[ReVW(4)O(19)]·7H(2)O, the Lindqvist-type polyoxido anion has crystallographically imposed mm2 symmetry and is built up by six MO(6) (M = W, V, Re) edge-sharing distorted octa­hedra. The Re and V atoms share the same crystallographic site in a 0.5:0.5 ratio. The 4-amino­pyridinium cations lie on a mirror plane. Three of the four independent water O atoms in the asymmetric unit are located on a mirror plane whereas the remaining O atom has mm2 site symmetry. In the crystal, the cations, anions and water mol­ecules are linked into a three-dimensional network through O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2013-11-16 /pmc/articles/PMC3884996/ /pubmed/24454171 http://dx.doi.org/10.1107/S1600536813030687 Text en © Maaloui et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maaloui, Ahlem
Toumi, Samah Akriche
Rzaigui, Mohamed
Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title_full Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title_fullStr Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title_full_unstemmed Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title_short Bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(VII)tetratungsten(VI)vanadium(V)]ate hepta­hydrate
title_sort bis(4-amino­pyridinium) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxido[rhenium(vii)tetratungsten(vi)vanadium(v)]ate hepta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884996/
https://www.ncbi.nlm.nih.gov/pubmed/24454171
http://dx.doi.org/10.1107/S1600536813030687
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