Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]

In the structure of the title complex, [Cs(C(7)H(4)NO(2))(H(2)O)(2)](n), the caesium salt of 4-nitro­benzoic acid, the irregular CsO(9) coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxyl­ate O,O′-chelate inter­action, a triple-bridging water mol­ecule and a monode...

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Detalles Bibliográficos
Autor principal: Smith, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884998/
https://www.ncbi.nlm.nih.gov/pubmed/24454173
http://dx.doi.org/10.1107/S1600536813030638
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author Smith, Graham
author_facet Smith, Graham
author_sort Smith, Graham
collection PubMed
description In the structure of the title complex, [Cs(C(7)H(4)NO(2))(H(2)O)(2)](n), the caesium salt of 4-nitro­benzoic acid, the irregular CsO(9) coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxyl­ate O,O′-chelate inter­action, a triple-bridging water mol­ecule and a monodentate water mol­ecule. A three-dimensional framework polymer is generated, within which there are water–carboxyl­ate O—H⋯O and water–water O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-38849982014-01-17 Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium] Smith, Graham Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cs(C(7)H(4)NO(2))(H(2)O)(2)](n), the caesium salt of 4-nitro­benzoic acid, the irregular CsO(9) coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxyl­ate O,O′-chelate inter­action, a triple-bridging water mol­ecule and a monodentate water mol­ecule. A three-dimensional framework polymer is generated, within which there are water–carboxyl­ate O—H⋯O and water–water O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2013-11-16 /pmc/articles/PMC3884998/ /pubmed/24454173 http://dx.doi.org/10.1107/S1600536813030638 Text en © Graham Smith 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Smith, Graham
Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title_full Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title_fullStr Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title_full_unstemmed Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title_short Poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
title_sort poly[μ(3)-aqua-aqua-μ(5)-(4-nitro­benzoato)-caesium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884998/
https://www.ncbi.nlm.nih.gov/pubmed/24454173
http://dx.doi.org/10.1107/S1600536813030638
work_keys_str_mv AT smithgraham polym3aquaaquam54nitrobenzoatocaesium

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