Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate

The asymmetric unit of the title compound, (C(6)H(20)N(3))[BiCl(6)]·H(2)O, consists of a triprotonated bis­(3-aza­niumylprop­yl)aza­nium cation, two halves of an octahedral [BiCl(6)](3−) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol­ecule. In the crystal, the anions...

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Detalles Bibliográficos
Autores principales: Elfaleh, Nizar, Chouaib, Hassen, Kamoun, Slaheddine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884999/
https://www.ncbi.nlm.nih.gov/pubmed/24454174
http://dx.doi.org/10.1107/S1600536813030900
Descripción
Sumario:The asymmetric unit of the title compound, (C(6)H(20)N(3))[BiCl(6)]·H(2)O, consists of a triprotonated bis­(3-aza­niumylprop­yl)aza­nium cation, two halves of an octahedral [BiCl(6)](3−) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol­ecule. In the crystal, the anions and water mol­ecules are linked by O—H⋯Cl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N—H⋯Cl and N—H⋯O hydrogen-bond inter­actions.

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